Cargando…
Bis(2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoato-κ(2) O,O′)bis(pyridine-κN)iron(II)
The title compound, [Fe(C(24)H(21)O(4)S(2))(2)(C(5)H(5)N)(2)], has 2 symmetry. The Fe(II) cation is located on a twofold rotation axis and is O,O′-chelated by two 2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoate anions and further coordinated by two pyridine ligands...
| Autores principales: | , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051472/ https://www.ncbi.nlm.nih.gov/pubmed/21522840 http://dx.doi.org/10.1107/S1600536810054619 |
| _version_ | 1782199487057362944 |
|---|---|
| author | Xu, Yu-Min Hu, Tuo-Ping |
| author_facet | Xu, Yu-Min Hu, Tuo-Ping |
| author_sort | Xu, Yu-Min |
| collection | PubMed |
| description | The title compound, [Fe(C(24)H(21)O(4)S(2))(2)(C(5)H(5)N)(2)], has 2 symmetry. The Fe(II) cation is located on a twofold rotation axis and is O,O′-chelated by two 2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoate anions and further coordinated by two pyridine ligands in a distorted octahedral geometry. In the anion, the terminal benzene rings are oriented at dihedral angles of 63.81 (14) and 84.50 (14)° with respect to the central benzene ring. Intermolecular O—H⋯O and C—H⋯O hydrogen bonding is present in the crystal structure. |
| format | Text |
| id | pubmed-3051472 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30514722011-04-26 Bis(2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoato-κ(2) O,O′)bis(pyridine-κN)iron(II) Xu, Yu-Min Hu, Tuo-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(24)H(21)O(4)S(2))(2)(C(5)H(5)N)(2)], has 2 symmetry. The Fe(II) cation is located on a twofold rotation axis and is O,O′-chelated by two 2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoate anions and further coordinated by two pyridine ligands in a distorted octahedral geometry. In the anion, the terminal benzene rings are oriented at dihedral angles of 63.81 (14) and 84.50 (14)° with respect to the central benzene ring. Intermolecular O—H⋯O and C—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2011-01-12 /pmc/articles/PMC3051472/ /pubmed/21522840 http://dx.doi.org/10.1107/S1600536810054619 Text en © Xu and Hu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xu, Yu-Min Hu, Tuo-Ping Bis(2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoato-κ(2) O,O′)bis(pyridine-κN)iron(II) |
| title | Bis(2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoato-κ(2)
O,O′)bis(pyridine-κN)iron(II) |
| title_full | Bis(2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoato-κ(2)
O,O′)bis(pyridine-κN)iron(II) |
| title_fullStr | Bis(2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoato-κ(2)
O,O′)bis(pyridine-κN)iron(II) |
| title_full_unstemmed | Bis(2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoato-κ(2)
O,O′)bis(pyridine-κN)iron(II) |
| title_short | Bis(2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoato-κ(2)
O,O′)bis(pyridine-κN)iron(II) |
| title_sort | bis(2-{5-[(2-carboxyphenyl)sulfanylmethyl]-2,4-dimethylbenzylsulfanyl}benzoato-κ(2)
o,o′)bis(pyridine-κn)iron(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051472/ https://www.ncbi.nlm.nih.gov/pubmed/21522840 http://dx.doi.org/10.1107/S1600536810054619 |
| work_keys_str_mv | AT xuyumin bis252carboxyphenylsulfanylmethyl24dimethylbenzylsulfanylbenzoatok2oobispyridineknironii AT hutuoping bis252carboxyphenylsulfanylmethyl24dimethylbenzylsulfanylbenzoatok2oobispyridineknironii |