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2,2-Dimethyl-5-{[(4-nitrophenyl)amino]methylidene}-1,3-dioxane-4,6-dione
In the title compound, C(13)H(12)N(2)O(6), the dihedral angle between the benzene ring and the aminomethylene unit is 5.42 (16)°, while the angle between the aminomethylene unit and the dioxane ring is 3.06 (43)°. The dioxane ring shows a half-boat conformation, in which the C atom between the d...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051475/ https://www.ncbi.nlm.nih.gov/pubmed/21523083 http://dx.doi.org/10.1107/S1600536811001103 |
Sumario: | In the title compound, C(13)H(12)N(2)O(6), the dihedral angle between the benzene ring and the aminomethylene unit is 5.42 (16)°, while the angle between the aminomethylene unit and the dioxane ring is 3.06 (43)°. The dioxane ring shows a half-boat conformation, in which the C atom between the dioxane ring O atoms is 0.464 (10) Å out of the plane. An intramolecular N—H⋯O hydrogen bond stabilizes the molecular conformation. In the crystal, a three-dimensional framework is built up via intermolecular N—H⋯O hydrogen bonds. |
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