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2,2-Dimethyl-5-{[(4-nitro­phen­yl)amino]­methyl­idene}-1,3-dioxane-4,6-dione

In the title compound, C(13)H(12)N(2)O(6), the dihedral angle between the benzene ring and the amino­methyl­ene unit is 5.42 (16)°, while the angle between the amino­methyl­ene unit and the dioxane ring is 3.06 (43)°. The dioxane ring shows a half-boat conformation, in which the C atom between the d...

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Detalles Bibliográficos
Autores principales: Yang, Ying-Hong, Li, Zi-Cheng, Luo, You-Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051475/
https://www.ncbi.nlm.nih.gov/pubmed/21523083
http://dx.doi.org/10.1107/S1600536811001103
Descripción
Sumario:In the title compound, C(13)H(12)N(2)O(6), the dihedral angle between the benzene ring and the amino­methyl­ene unit is 5.42 (16)°, while the angle between the amino­methyl­ene unit and the dioxane ring is 3.06 (43)°. The dioxane ring shows a half-boat conformation, in which the C atom between the dioxane ring O atoms is 0.464 (10) Å out of the plane. An intra­molecular N—H⋯O hydrogen bond stabilizes the mol­ecular conformation. In the crystal, a three-dimensional framework is built up via inter­molecular N—H⋯O hydrogen bonds.