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2,2-Dimethyl-5-{[(4-nitro­phen­yl)amino]­methyl­idene}-1,3-dioxane-4,6-dione

In the title compound, C(13)H(12)N(2)O(6), the dihedral angle between the benzene ring and the amino­methyl­ene unit is 5.42 (16)°, while the angle between the amino­methyl­ene unit and the dioxane ring is 3.06 (43)°. The dioxane ring shows a half-boat conformation, in which the C atom between the d...

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Detalles Bibliográficos
Autores principales: Yang, Ying-Hong, Li, Zi-Cheng, Luo, You-Fu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051475/
https://www.ncbi.nlm.nih.gov/pubmed/21523083
http://dx.doi.org/10.1107/S1600536811001103
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author Yang, Ying-Hong
Li, Zi-Cheng
Luo, You-Fu
author_facet Yang, Ying-Hong
Li, Zi-Cheng
Luo, You-Fu
author_sort Yang, Ying-Hong
collection PubMed
description In the title compound, C(13)H(12)N(2)O(6), the dihedral angle between the benzene ring and the amino­methyl­ene unit is 5.42 (16)°, while the angle between the amino­methyl­ene unit and the dioxane ring is 3.06 (43)°. The dioxane ring shows a half-boat conformation, in which the C atom between the dioxane ring O atoms is 0.464 (10) Å out of the plane. An intra­molecular N—H⋯O hydrogen bond stabilizes the mol­ecular conformation. In the crystal, a three-dimensional framework is built up via inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-30514752011-04-26 2,2-Dimethyl-5-{[(4-nitro­phen­yl)amino]­methyl­idene}-1,3-dioxane-4,6-dione Yang, Ying-Hong Li, Zi-Cheng Luo, You-Fu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(12)N(2)O(6), the dihedral angle between the benzene ring and the amino­methyl­ene unit is 5.42 (16)°, while the angle between the amino­methyl­ene unit and the dioxane ring is 3.06 (43)°. The dioxane ring shows a half-boat conformation, in which the C atom between the dioxane ring O atoms is 0.464 (10) Å out of the plane. An intra­molecular N—H⋯O hydrogen bond stabilizes the mol­ecular conformation. In the crystal, a three-dimensional framework is built up via inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051475/ /pubmed/21523083 http://dx.doi.org/10.1107/S1600536811001103 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Ying-Hong
Li, Zi-Cheng
Luo, You-Fu
2,2-Dimethyl-5-{[(4-nitro­phen­yl)amino]­methyl­idene}-1,3-dioxane-4,6-dione
title 2,2-Dimethyl-5-{[(4-nitro­phen­yl)amino]­methyl­idene}-1,3-dioxane-4,6-dione
title_full 2,2-Dimethyl-5-{[(4-nitro­phen­yl)amino]­methyl­idene}-1,3-dioxane-4,6-dione
title_fullStr 2,2-Dimethyl-5-{[(4-nitro­phen­yl)amino]­methyl­idene}-1,3-dioxane-4,6-dione
title_full_unstemmed 2,2-Dimethyl-5-{[(4-nitro­phen­yl)amino]­methyl­idene}-1,3-dioxane-4,6-dione
title_short 2,2-Dimethyl-5-{[(4-nitro­phen­yl)amino]­methyl­idene}-1,3-dioxane-4,6-dione
title_sort 2,2-dimethyl-5-{[(4-nitro­phen­yl)amino]­methyl­idene}-1,3-dioxane-4,6-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051475/
https://www.ncbi.nlm.nih.gov/pubmed/21523083
http://dx.doi.org/10.1107/S1600536811001103
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