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2,2-Dimethyl-5-{[(4-nitrophenyl)amino]methylidene}-1,3-dioxane-4,6-dione
In the title compound, C(13)H(12)N(2)O(6), the dihedral angle between the benzene ring and the aminomethylene unit is 5.42 (16)°, while the angle between the aminomethylene unit and the dioxane ring is 3.06 (43)°. The dioxane ring shows a half-boat conformation, in which the C atom between the d...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051475/ https://www.ncbi.nlm.nih.gov/pubmed/21523083 http://dx.doi.org/10.1107/S1600536811001103 |
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author | Yang, Ying-Hong Li, Zi-Cheng Luo, You-Fu |
author_facet | Yang, Ying-Hong Li, Zi-Cheng Luo, You-Fu |
author_sort | Yang, Ying-Hong |
collection | PubMed |
description | In the title compound, C(13)H(12)N(2)O(6), the dihedral angle between the benzene ring and the aminomethylene unit is 5.42 (16)°, while the angle between the aminomethylene unit and the dioxane ring is 3.06 (43)°. The dioxane ring shows a half-boat conformation, in which the C atom between the dioxane ring O atoms is 0.464 (10) Å out of the plane. An intramolecular N—H⋯O hydrogen bond stabilizes the molecular conformation. In the crystal, a three-dimensional framework is built up via intermolecular N—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-3051475 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30514752011-04-26 2,2-Dimethyl-5-{[(4-nitrophenyl)amino]methylidene}-1,3-dioxane-4,6-dione Yang, Ying-Hong Li, Zi-Cheng Luo, You-Fu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(12)N(2)O(6), the dihedral angle between the benzene ring and the aminomethylene unit is 5.42 (16)°, while the angle between the aminomethylene unit and the dioxane ring is 3.06 (43)°. The dioxane ring shows a half-boat conformation, in which the C atom between the dioxane ring O atoms is 0.464 (10) Å out of the plane. An intramolecular N—H⋯O hydrogen bond stabilizes the molecular conformation. In the crystal, a three-dimensional framework is built up via intermolecular N—H⋯O hydrogen bonds. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051475/ /pubmed/21523083 http://dx.doi.org/10.1107/S1600536811001103 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yang, Ying-Hong Li, Zi-Cheng Luo, You-Fu 2,2-Dimethyl-5-{[(4-nitrophenyl)amino]methylidene}-1,3-dioxane-4,6-dione |
title | 2,2-Dimethyl-5-{[(4-nitrophenyl)amino]methylidene}-1,3-dioxane-4,6-dione |
title_full | 2,2-Dimethyl-5-{[(4-nitrophenyl)amino]methylidene}-1,3-dioxane-4,6-dione |
title_fullStr | 2,2-Dimethyl-5-{[(4-nitrophenyl)amino]methylidene}-1,3-dioxane-4,6-dione |
title_full_unstemmed | 2,2-Dimethyl-5-{[(4-nitrophenyl)amino]methylidene}-1,3-dioxane-4,6-dione |
title_short | 2,2-Dimethyl-5-{[(4-nitrophenyl)amino]methylidene}-1,3-dioxane-4,6-dione |
title_sort | 2,2-dimethyl-5-{[(4-nitrophenyl)amino]methylidene}-1,3-dioxane-4,6-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051475/ https://www.ncbi.nlm.nih.gov/pubmed/21523083 http://dx.doi.org/10.1107/S1600536811001103 |
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