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catena-Poly[[diaqua­cobalt(II)]-μ-4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ato-κ(4) O,O′:O′′,O′′′]

In the title coordination polymer, [Co(C(14)H(16)O(6))(H(2)O)(2)](n), the Co(II) ion, situated on a twofold rotation axis, is coordinated by four O atoms from two 4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ate (L) ligands and two water mol­ecules in a highly distorted octa­hedral geometry. Each L ligand...

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Autor principal: Zhao, Ying-Ying
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051477/
https://www.ncbi.nlm.nih.gov/pubmed/21522824
http://dx.doi.org/10.1107/S1600536810053742
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author Zhao, Ying-Ying
author_facet Zhao, Ying-Ying
author_sort Zhao, Ying-Ying
collection PubMed
description In the title coordination polymer, [Co(C(14)H(16)O(6))(H(2)O)(2)](n), the Co(II) ion, situated on a twofold rotation axis, is coordinated by four O atoms from two 4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ate (L) ligands and two water mol­ecules in a highly distorted octa­hedral geometry. Each L ligand is situated on an inversion center and bridges two Co(II) atoms, forming a zigzag polymeric chain propagating in [10[Image: see text]]. Inter­molecular O—H⋯O hydrogen bonds further consolidate the crystal packing.
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spelling pubmed-30514772011-04-26 catena-Poly[[diaqua­cobalt(II)]-μ-4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ato-κ(4) O,O′:O′′,O′′′] Zhao, Ying-Ying Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Co(C(14)H(16)O(6))(H(2)O)(2)](n), the Co(II) ion, situated on a twofold rotation axis, is coordinated by four O atoms from two 4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ate (L) ligands and two water mol­ecules in a highly distorted octa­hedral geometry. Each L ligand is situated on an inversion center and bridges two Co(II) atoms, forming a zigzag polymeric chain propagating in [10[Image: see text]]. Inter­molecular O—H⋯O hydrogen bonds further consolidate the crystal packing. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051477/ /pubmed/21522824 http://dx.doi.org/10.1107/S1600536810053742 Text en © Ying-Ying Zhao 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Ying-Ying
catena-Poly[[diaqua­cobalt(II)]-μ-4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ato-κ(4) O,O′:O′′,O′′′]
title catena-Poly[[diaqua­cobalt(II)]-μ-4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ato-κ(4) O,O′:O′′,O′′′]
title_full catena-Poly[[diaqua­cobalt(II)]-μ-4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ato-κ(4) O,O′:O′′,O′′′]
title_fullStr catena-Poly[[diaqua­cobalt(II)]-μ-4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ato-κ(4) O,O′:O′′,O′′′]
title_full_unstemmed catena-Poly[[diaqua­cobalt(II)]-μ-4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ato-κ(4) O,O′:O′′,O′′′]
title_short catena-Poly[[diaqua­cobalt(II)]-μ-4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ato-κ(4) O,O′:O′′,O′′′]
title_sort catena-poly[[diaqua­cobalt(ii)]-μ-4,4′-[1,4-phenyl­enebis(­oxy)]dibutano­ato-κ(4) o,o′:o′′,o′′′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051477/
https://www.ncbi.nlm.nih.gov/pubmed/21522824
http://dx.doi.org/10.1107/S1600536810053742
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