N-Cyclo­hexyl­cyclo­hexa­naminium chloride

In the title salt, C(12)H(24)N(+)·Cl(−), both cyclo­hexyl rings adopt chair conformations and the NH(2) unit is situated in the equatorial position with respect to the rings in the cation. The large C—N—C bond angle [117.99 (14)°] in the cation is a result of linking two bulky cyclo­hexyl rings to t...

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Detalles Bibliográficos
Autores principales: Pourayoubi, Mehrdad, Negari, Monireh, Nečas, Marek
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051479/
https://www.ncbi.nlm.nih.gov/pubmed/21523016
http://dx.doi.org/10.1107/S1600536811000857
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author Pourayoubi, Mehrdad
Negari, Monireh
Nečas, Marek
author_facet Pourayoubi, Mehrdad
Negari, Monireh
Nečas, Marek
author_sort Pourayoubi, Mehrdad
collection PubMed
description In the title salt, C(12)H(24)N(+)·Cl(−), both cyclo­hexyl rings adopt chair conformations and the NH(2) unit is situated in the equatorial position with respect to the rings in the cation. The large C—N—C bond angle [117.99 (14)°] in the cation is a result of linking two bulky cyclo­hexyl rings to the N atom. The aminium H atoms are involved in inter­molecular N—H⋯Cl hydrogen bonds, forming an infinite zigzag chain parallel to the c axis. The crystal studied was a racemic twin with a twin fraction of 0.28 (18).
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spelling pubmed-30514792011-04-26 N-Cyclo­hexyl­cyclo­hexa­naminium chloride Pourayoubi, Mehrdad Negari, Monireh Nečas, Marek Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(12)H(24)N(+)·Cl(−), both cyclo­hexyl rings adopt chair conformations and the NH(2) unit is situated in the equatorial position with respect to the rings in the cation. The large C—N—C bond angle [117.99 (14)°] in the cation is a result of linking two bulky cyclo­hexyl rings to the N atom. The aminium H atoms are involved in inter­molecular N—H⋯Cl hydrogen bonds, forming an infinite zigzag chain parallel to the c axis. The crystal studied was a racemic twin with a twin fraction of 0.28 (18). International Union of Crystallography 2011-01-12 /pmc/articles/PMC3051479/ /pubmed/21523016 http://dx.doi.org/10.1107/S1600536811000857 Text en © Pourayoubi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Pourayoubi, Mehrdad
Negari, Monireh
Nečas, Marek
N-Cyclo­hexyl­cyclo­hexa­naminium chloride
title N-Cyclo­hexyl­cyclo­hexa­naminium chloride
title_full N-Cyclo­hexyl­cyclo­hexa­naminium chloride
title_fullStr N-Cyclo­hexyl­cyclo­hexa­naminium chloride
title_full_unstemmed N-Cyclo­hexyl­cyclo­hexa­naminium chloride
title_short N-Cyclo­hexyl­cyclo­hexa­naminium chloride
title_sort n-cyclo­hexyl­cyclo­hexa­naminium chloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051479/
https://www.ncbi.nlm.nih.gov/pubmed/21523016
http://dx.doi.org/10.1107/S1600536811000857
work_keys_str_mv AT pourayoubimehrdad ncyclohexylcyclohexanaminiumchloride
AT negarimonireh ncyclohexylcyclohexanaminiumchloride
AT necasmarek ncyclohexylcyclohexanaminiumchloride

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