N,N-Bis(diphenyl­phosphan­yl)benzyl­amine

In the title compound, C(31)H(27)NP(2), the diphenyl­phosphanyl groups are staggered relative to the PNP backbone. The N atom is displaced by 0.219 (2) Å from the plane formed by the two P atoms and the methylene C atom. The angles around the N atom are 120.84 (16), 113.29 (16) and 120.57 (12)°, ind...

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Detalles Bibliográficos
Autores principales: Liu, Xu-Feng, Xu, Wei-Hong, Li, Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051494/
https://www.ncbi.nlm.nih.gov/pubmed/21523048
http://dx.doi.org/10.1107/S1600536811000997
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author Liu, Xu-Feng
Xu, Wei-Hong
Li, Hui
author_facet Liu, Xu-Feng
Xu, Wei-Hong
Li, Hui
author_sort Liu, Xu-Feng
collection PubMed
description In the title compound, C(31)H(27)NP(2), the diphenyl­phosphanyl groups are staggered relative to the PNP backbone. The N atom is displaced by 0.219 (2) Å from the plane formed by the two P atoms and the methylene C atom. The angles around the N atom are 120.84 (16), 113.29 (16) and 120.57 (12)°, indicating that it exhibits a distorted trigonal–pyramidal geometry. There are no classical inter­molecular inter­actions.
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spelling pubmed-30514942011-04-26 N,N-Bis(diphenyl­phosphan­yl)benzyl­amine Liu, Xu-Feng Xu, Wei-Hong Li, Hui Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(31)H(27)NP(2), the diphenyl­phosphanyl groups are staggered relative to the PNP backbone. The N atom is displaced by 0.219 (2) Å from the plane formed by the two P atoms and the methylene C atom. The angles around the N atom are 120.84 (16), 113.29 (16) and 120.57 (12)°, indicating that it exhibits a distorted trigonal–pyramidal geometry. There are no classical inter­molecular inter­actions. International Union of Crystallography 2011-01-12 /pmc/articles/PMC3051494/ /pubmed/21523048 http://dx.doi.org/10.1107/S1600536811000997 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Xu-Feng
Xu, Wei-Hong
Li, Hui
N,N-Bis(diphenyl­phosphan­yl)benzyl­amine
title N,N-Bis(diphenyl­phosphan­yl)benzyl­amine
title_full N,N-Bis(diphenyl­phosphan­yl)benzyl­amine
title_fullStr N,N-Bis(diphenyl­phosphan­yl)benzyl­amine
title_full_unstemmed N,N-Bis(diphenyl­phosphan­yl)benzyl­amine
title_short N,N-Bis(diphenyl­phosphan­yl)benzyl­amine
title_sort n,n-bis(diphenyl­phosphan­yl)benzyl­amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051494/
https://www.ncbi.nlm.nih.gov/pubmed/21523048
http://dx.doi.org/10.1107/S1600536811000997
work_keys_str_mv AT liuxufeng nnbisdiphenylphosphanylbenzylamine
AT xuweihong nnbisdiphenylphosphanylbenzylamine
AT lihui nnbisdiphenylphosphanylbenzylamine

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