Deltaline from Delphinium delavayi Franch

The title compound [systematic name: 6β,10-dihy­droxy-1α,14α,16β-trimeth­oxy-4-methyl-7β,8-(methyl­enedi­oxy)-20-ethyl­aconitan-6-yl acetate], C(27)H(41)NO(8), is a C(19)-diterpenoid alkaloid and a major diterpenoid alkaloid component of the roots of Delphinium delavayi Franch. var. pogonanthum (Han...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Xiong-Qing, Song, Qin, Guo, Xiao-Qiang, Yan, Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051497/
https://www.ncbi.nlm.nih.gov/pubmed/21523103
http://dx.doi.org/10.1107/S1600536811001681
_version_ 1782199493055217664
author Wang, Xiong-Qing
Song, Qin
Guo, Xiao-Qiang
Yan, Jun
author_facet Wang, Xiong-Qing
Song, Qin
Guo, Xiao-Qiang
Yan, Jun
author_sort Wang, Xiong-Qing
collection PubMed
description The title compound [systematic name: 6β,10-dihy­droxy-1α,14α,16β-trimeth­oxy-4-methyl-7β,8-(methyl­enedi­oxy)-20-ethyl­aconitan-6-yl acetate], C(27)H(41)NO(8), is a C(19)-diterpenoid alkaloid and a major diterpenoid alkaloid component of the roots of Delphinium delavayi Franch. var. pogonanthum (Hand.-Mazz.) W. T. Wang. The mol­ecule has a lycoctonine carbon-atom skeleton with four six-membered rings and three five-membered rings among; three of the six-membered rings adopt chair conformations with the fourth adopting a boat conformation while all of the five-membered rings exhibit envelope conformations. Inter­molecular O—H⋯O hydrogen bonding is present in the crystal structure.
format Text
id pubmed-3051497
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30514972011-04-26 Deltaline from Delphinium delavayi Franch Wang, Xiong-Qing Song, Qin Guo, Xiao-Qiang Yan, Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound [systematic name: 6β,10-dihy­droxy-1α,14α,16β-trimeth­oxy-4-methyl-7β,8-(methyl­enedi­oxy)-20-ethyl­aconitan-6-yl acetate], C(27)H(41)NO(8), is a C(19)-diterpenoid alkaloid and a major diterpenoid alkaloid component of the roots of Delphinium delavayi Franch. var. pogonanthum (Hand.-Mazz.) W. T. Wang. The mol­ecule has a lycoctonine carbon-atom skeleton with four six-membered rings and three five-membered rings among; three of the six-membered rings adopt chair conformations with the fourth adopting a boat conformation while all of the five-membered rings exhibit envelope conformations. Inter­molecular O—H⋯O hydrogen bonding is present in the crystal structure. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051497/ /pubmed/21523103 http://dx.doi.org/10.1107/S1600536811001681 Text en © Wang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Xiong-Qing
Song, Qin
Guo, Xiao-Qiang
Yan, Jun
Deltaline from Delphinium delavayi Franch
title Deltaline from Delphinium delavayi Franch
title_full Deltaline from Delphinium delavayi Franch
title_fullStr Deltaline from Delphinium delavayi Franch
title_full_unstemmed Deltaline from Delphinium delavayi Franch
title_short Deltaline from Delphinium delavayi Franch
title_sort deltaline from delphinium delavayi franch
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051497/
https://www.ncbi.nlm.nih.gov/pubmed/21523103
http://dx.doi.org/10.1107/S1600536811001681
work_keys_str_mv AT wangxiongqing deltalinefromdelphiniumdelavayifranch
AT songqin deltalinefromdelphiniumdelavayifranch
AT guoxiaoqiang deltalinefromdelphiniumdelavayifranch
AT yanjun deltalinefromdelphiniumdelavayifranch

Ejemplares similares