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[μ-2-(4-Hydroxyphenyl)acetato]-κ(3) O:O,O′;κ(3) O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]holmium(III)} monohydrate
In the title dinuclear complex, [Ho(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, each of the two independent Ho(III) ions is coordinated by eight O atoms from four 4-hydroxyphenylacetate (HPAA) ligands and a water molecule, and one N atom from a 4,4′-bipyridine (bipy) ligand in a dist...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051499/ https://www.ncbi.nlm.nih.gov/pubmed/21522861 http://dx.doi.org/10.1107/S1600536811001115 |
| _version_ | 1782199493522882560 |
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| author | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
| author_facet | Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang |
| author_sort | Liu, Jia-Lu |
| collection | PubMed |
| description | In the title dinuclear complex, [Ho(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, each of the two independent Ho(III) ions is coordinated by eight O atoms from four 4-hydroxyphenylacetate (HPAA) ligands and a water molecule, and one N atom from a 4,4′-bipyridine (bipy) ligand in a distorted tricapped trigonal–prismatic geometry. The HPAA ligands are coordinated in bis-chelate, bridging and bridging tridentate modes. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds link the molecules into a three-dimensional network. |
| format | Text |
| id | pubmed-3051499 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30514992011-04-26 [μ-2-(4-Hydroxyphenyl)acetato]-κ(3) O:O,O′;κ(3) O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]holmium(III)} monohydrate Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear complex, [Ho(2)(C(8)H(7)O(3))(6)(C(10)H(8)N(2))(2)(H(2)O)(2)]·H(2)O, each of the two independent Ho(III) ions is coordinated by eight O atoms from four 4-hydroxyphenylacetate (HPAA) ligands and a water molecule, and one N atom from a 4,4′-bipyridine (bipy) ligand in a distorted tricapped trigonal–prismatic geometry. The HPAA ligands are coordinated in bis-chelate, bridging and bridging tridentate modes. In the crystal, O—H⋯O and O—H⋯N hydrogen bonds link the molecules into a three-dimensional network. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051499/ /pubmed/21522861 http://dx.doi.org/10.1107/S1600536811001115 Text en © Liu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Jia-Lu Liu, Jian-Feng Zhao, Guo-Liang [μ-2-(4-Hydroxyphenyl)acetato]-κ(3) O:O,O′;κ(3) O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2) O,O′]holmium(III)} monohydrate |
| title | [μ-2-(4-Hydroxyphenyl)acetato]-κ(3)
O:O,O′;κ(3)
O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]holmium(III)} monohydrate |
| title_full | [μ-2-(4-Hydroxyphenyl)acetato]-κ(3)
O:O,O′;κ(3)
O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]holmium(III)} monohydrate |
| title_fullStr | [μ-2-(4-Hydroxyphenyl)acetato]-κ(3)
O:O,O′;κ(3)
O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]holmium(III)} monohydrate |
| title_full_unstemmed | [μ-2-(4-Hydroxyphenyl)acetato]-κ(3)
O:O,O′;κ(3)
O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]holmium(III)} monohydrate |
| title_short | [μ-2-(4-Hydroxyphenyl)acetato]-κ(3)
O:O,O′;κ(3)
O,O′:O′-bis{aqua(4,4′-bipyridine-κN)bis[2-(4-hydroxyphenyl)acetato-κ(2)
O,O′]holmium(III)} monohydrate |
| title_sort | [μ-2-(4-hydroxyphenyl)acetato]-κ(3)
o:o,o′;κ(3)
o,o′:o′-bis{aqua(4,4′-bipyridine-κn)bis[2-(4-hydroxyphenyl)acetato-κ(2)
o,o′]holmium(iii)} monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051499/ https://www.ncbi.nlm.nih.gov/pubmed/21522861 http://dx.doi.org/10.1107/S1600536811001115 |
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