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Bis(2-{[2-(isopropylazaniumyl)ethyl]iminomethyl}-6-methoxyphenolato)copper(II) bis(thiocyanate)
The asymmetric unit of the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](NCS)(2), contains one half-dication, located on an inversion center, and one thiocyanate anion. Each Cu(II) atom is four-coordinated by two phenolate O and two imine N atoms from two symmetry-related Schiff base 2-{[2-(isopropyl...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051500/ https://www.ncbi.nlm.nih.gov/pubmed/21522866 http://dx.doi.org/10.1107/S1600536811001322 |
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author | Yuan, Lin |
author_facet | Yuan, Lin |
author_sort | Yuan, Lin |
collection | PubMed |
description | The asymmetric unit of the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](NCS)(2), contains one half-dication, located on an inversion center, and one thiocyanate anion. Each Cu(II) atom is four-coordinated by two phenolate O and two imine N atoms from two symmetry-related Schiff base 2-{[2-(isopropylazaniumyl)ethyl]iminomethyl}-6-methoxyphenolate (L) ligands in a distorted square-planar geometry. The ammonium groups are involved in the formation of N—H⋯O and N—H⋯N hydrogen bonds, which link one dication and two anions into an electroneutral cluster. When very weak Cu—N interactions with a distance of 2.910 (5) Å between the metal and the thiocyanate anions in apical positions are considered, the secondary coordination polyhedron is a very elongated CuN(4)O(2) octahedron. |
format | Text |
id | pubmed-3051500 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30515002011-04-26 Bis(2-{[2-(isopropylazaniumyl)ethyl]iminomethyl}-6-methoxyphenolato)copper(II) bis(thiocyanate) Yuan, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](NCS)(2), contains one half-dication, located on an inversion center, and one thiocyanate anion. Each Cu(II) atom is four-coordinated by two phenolate O and two imine N atoms from two symmetry-related Schiff base 2-{[2-(isopropylazaniumyl)ethyl]iminomethyl}-6-methoxyphenolate (L) ligands in a distorted square-planar geometry. The ammonium groups are involved in the formation of N—H⋯O and N—H⋯N hydrogen bonds, which link one dication and two anions into an electroneutral cluster. When very weak Cu—N interactions with a distance of 2.910 (5) Å between the metal and the thiocyanate anions in apical positions are considered, the secondary coordination polyhedron is a very elongated CuN(4)O(2) octahedron. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051500/ /pubmed/21522866 http://dx.doi.org/10.1107/S1600536811001322 Text en © Lin Yuan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yuan, Lin Bis(2-{[2-(isopropylazaniumyl)ethyl]iminomethyl}-6-methoxyphenolato)copper(II) bis(thiocyanate) |
title | Bis(2-{[2-(isopropylazaniumyl)ethyl]iminomethyl}-6-methoxyphenolato)copper(II) bis(thiocyanate) |
title_full | Bis(2-{[2-(isopropylazaniumyl)ethyl]iminomethyl}-6-methoxyphenolato)copper(II) bis(thiocyanate) |
title_fullStr | Bis(2-{[2-(isopropylazaniumyl)ethyl]iminomethyl}-6-methoxyphenolato)copper(II) bis(thiocyanate) |
title_full_unstemmed | Bis(2-{[2-(isopropylazaniumyl)ethyl]iminomethyl}-6-methoxyphenolato)copper(II) bis(thiocyanate) |
title_short | Bis(2-{[2-(isopropylazaniumyl)ethyl]iminomethyl}-6-methoxyphenolato)copper(II) bis(thiocyanate) |
title_sort | bis(2-{[2-(isopropylazaniumyl)ethyl]iminomethyl}-6-methoxyphenolato)copper(ii) bis(thiocyanate) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051500/ https://www.ncbi.nlm.nih.gov/pubmed/21522866 http://dx.doi.org/10.1107/S1600536811001322 |
work_keys_str_mv | AT yuanlin bis22isopropylazaniumylethyliminomethyl6methoxyphenolatocopperiibisthiocyanate |