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Bis(2-{[2-(isopropyl­aza­nium­yl)eth­yl]imino­meth­yl}-6-meth­oxy­phenolato)copper(II) bis­(thio­cyanate)

The asymmetric unit of the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](NCS)(2), contains one half-dication, located on an inversion center, and one thio­cyanate anion. Each Cu(II) atom is four-coordinated by two phenolate O and two imine N atoms from two symmetry-related Schiff base 2-{[2-(isopropyl...

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Detalles Bibliográficos
Autor principal: Yuan, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051500/
https://www.ncbi.nlm.nih.gov/pubmed/21522866
http://dx.doi.org/10.1107/S1600536811001322
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author Yuan, Lin
author_facet Yuan, Lin
author_sort Yuan, Lin
collection PubMed
description The asymmetric unit of the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](NCS)(2), contains one half-dication, located on an inversion center, and one thio­cyanate anion. Each Cu(II) atom is four-coordinated by two phenolate O and two imine N atoms from two symmetry-related Schiff base 2-{[2-(isopropyl­aza­nium­yl)eth­yl]imino­meth­yl}-6-meth­oxy­phenolate (L) ligands in a distorted square-planar geometry. The ammonium groups are involved in the formation of N—H⋯O and N—H⋯N hydrogen bonds, which link one dication and two anions into an electroneutral cluster. When very weak Cu—N interactions with a distance of 2.910 (5) Å between the metal and the thiocyanate anions in apical positions are considered, the secondary coordination polyhedron is a very elongated CuN(4)O(2) octahedron.
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spelling pubmed-30515002011-04-26 Bis(2-{[2-(isopropyl­aza­nium­yl)eth­yl]imino­meth­yl}-6-meth­oxy­phenolato)copper(II) bis­(thio­cyanate) Yuan, Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](NCS)(2), contains one half-dication, located on an inversion center, and one thio­cyanate anion. Each Cu(II) atom is four-coordinated by two phenolate O and two imine N atoms from two symmetry-related Schiff base 2-{[2-(isopropyl­aza­nium­yl)eth­yl]imino­meth­yl}-6-meth­oxy­phenolate (L) ligands in a distorted square-planar geometry. The ammonium groups are involved in the formation of N—H⋯O and N—H⋯N hydrogen bonds, which link one dication and two anions into an electroneutral cluster. When very weak Cu—N interactions with a distance of 2.910 (5) Å between the metal and the thiocyanate anions in apical positions are considered, the secondary coordination polyhedron is a very elongated CuN(4)O(2) octahedron. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051500/ /pubmed/21522866 http://dx.doi.org/10.1107/S1600536811001322 Text en © Lin Yuan 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yuan, Lin
Bis(2-{[2-(isopropyl­aza­nium­yl)eth­yl]imino­meth­yl}-6-meth­oxy­phenolato)copper(II) bis­(thio­cyanate)
title Bis(2-{[2-(isopropyl­aza­nium­yl)eth­yl]imino­meth­yl}-6-meth­oxy­phenolato)copper(II) bis­(thio­cyanate)
title_full Bis(2-{[2-(isopropyl­aza­nium­yl)eth­yl]imino­meth­yl}-6-meth­oxy­phenolato)copper(II) bis­(thio­cyanate)
title_fullStr Bis(2-{[2-(isopropyl­aza­nium­yl)eth­yl]imino­meth­yl}-6-meth­oxy­phenolato)copper(II) bis­(thio­cyanate)
title_full_unstemmed Bis(2-{[2-(isopropyl­aza­nium­yl)eth­yl]imino­meth­yl}-6-meth­oxy­phenolato)copper(II) bis­(thio­cyanate)
title_short Bis(2-{[2-(isopropyl­aza­nium­yl)eth­yl]imino­meth­yl}-6-meth­oxy­phenolato)copper(II) bis­(thio­cyanate)
title_sort bis(2-{[2-(isopropyl­aza­nium­yl)eth­yl]imino­meth­yl}-6-meth­oxy­phenolato)copper(ii) bis­(thio­cyanate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051500/
https://www.ncbi.nlm.nih.gov/pubmed/21522866
http://dx.doi.org/10.1107/S1600536811001322
work_keys_str_mv AT yuanlin bis22isopropylazaniumylethyliminomethyl6methoxyphenolatocopperiibisthiocyanate