(1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acet­oxy-2-phenyl­ethen­yl]-3-eth­oxy-2-phenyl­bicyclo­[3.1.0]hexan-1-yl acetate

The mol­ecule of the title compound, C(26)H(28)O(5), is chiral with five stereogenic centres; however, the centrosymmetric triclinic group gives a racemic crystal. The fused ring system adopta boat conformation in which the cyclo­propane ring plane is roughly perpendicular to the styryl group plane,...

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Detalles Bibliográficos
Autores principales: Hu, Wen-Xiang, Xu, Gao, Wei, Guo-Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051501/
https://www.ncbi.nlm.nih.gov/pubmed/21523163
http://dx.doi.org/10.1107/S1600536811001760
Descripción
Sumario:The mol­ecule of the title compound, C(26)H(28)O(5), is chiral with five stereogenic centres; however, the centrosymmetric triclinic group gives a racemic crystal. The fused ring system adopta boat conformation in which the cyclo­propane ring plane is roughly perpendicular to the styryl group plane, forming a dihedral angle of 74.78 (19)°. The dihedral angle between the two benzene rings is 77.24 (6)°.

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