(1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acet­oxy-2-phenyl­ethen­yl]-3-eth­oxy-2-phenyl­bicyclo­[3.1.0]hexan-1-yl acetate

The mol­ecule of the title compound, C(26)H(28)O(5), is chiral with five stereogenic centres; however, the centrosymmetric triclinic group gives a racemic crystal. The fused ring system adopta boat conformation in which the cyclo­propane ring plane is roughly perpendicular to the styryl group plane,...

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Detalles Bibliográficos
Autores principales: Hu, Wen-Xiang, Xu, Gao, Wei, Guo-Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051501/
https://www.ncbi.nlm.nih.gov/pubmed/21523163
http://dx.doi.org/10.1107/S1600536811001760
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author Hu, Wen-Xiang
Xu, Gao
Wei, Guo-Qiang
author_facet Hu, Wen-Xiang
Xu, Gao
Wei, Guo-Qiang
author_sort Hu, Wen-Xiang
collection PubMed
description The mol­ecule of the title compound, C(26)H(28)O(5), is chiral with five stereogenic centres; however, the centrosymmetric triclinic group gives a racemic crystal. The fused ring system adopta boat conformation in which the cyclo­propane ring plane is roughly perpendicular to the styryl group plane, forming a dihedral angle of 74.78 (19)°. The dihedral angle between the two benzene rings is 77.24 (6)°.
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spelling pubmed-30515012011-04-26 (1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acet­oxy-2-phenyl­ethen­yl]-3-eth­oxy-2-phenyl­bicyclo­[3.1.0]hexan-1-yl acetate Hu, Wen-Xiang Xu, Gao Wei, Guo-Qiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(26)H(28)O(5), is chiral with five stereogenic centres; however, the centrosymmetric triclinic group gives a racemic crystal. The fused ring system adopta boat conformation in which the cyclo­propane ring plane is roughly perpendicular to the styryl group plane, forming a dihedral angle of 74.78 (19)°. The dihedral angle between the two benzene rings is 77.24 (6)°. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051501/ /pubmed/21523163 http://dx.doi.org/10.1107/S1600536811001760 Text en © Hu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hu, Wen-Xiang
Xu, Gao
Wei, Guo-Qiang
(1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acet­oxy-2-phenyl­ethen­yl]-3-eth­oxy-2-phenyl­bicyclo­[3.1.0]hexan-1-yl acetate
title (1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acet­oxy-2-phenyl­ethen­yl]-3-eth­oxy-2-phenyl­bicyclo­[3.1.0]hexan-1-yl acetate
title_full (1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acet­oxy-2-phenyl­ethen­yl]-3-eth­oxy-2-phenyl­bicyclo­[3.1.0]hexan-1-yl acetate
title_fullStr (1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acet­oxy-2-phenyl­ethen­yl]-3-eth­oxy-2-phenyl­bicyclo­[3.1.0]hexan-1-yl acetate
title_full_unstemmed (1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acet­oxy-2-phenyl­ethen­yl]-3-eth­oxy-2-phenyl­bicyclo­[3.1.0]hexan-1-yl acetate
title_short (1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acet­oxy-2-phenyl­ethen­yl]-3-eth­oxy-2-phenyl­bicyclo­[3.1.0]hexan-1-yl acetate
title_sort (1sr,2rs,3sr,5sr,6rs)-6-[(z)-1-acet­oxy-2-phenyl­ethen­yl]-3-eth­oxy-2-phenyl­bicyclo­[3.1.0]hexan-1-yl acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051501/
https://www.ncbi.nlm.nih.gov/pubmed/21523163
http://dx.doi.org/10.1107/S1600536811001760
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AT xugao 1sr2rs3sr5sr6rs6z1acetoxy2phenylethenyl3ethoxy2phenylbicyclo310hexan1ylacetate
AT weiguoqiang 1sr2rs3sr5sr6rs6z1acetoxy2phenylethenyl3ethoxy2phenylbicyclo310hexan1ylacetate

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