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Aqua{2-morpholino-N-[1-(2-pyridyl)ethylidene]ethanamine-κ(3) N,N′,N′′}bis(thiocyanato-κN)cobalt(II)
In the title complex, [Co(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Co(II) ion is six-coordinated by the N,N′,N′′-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water molecule in a distorted octahedral geometry. Intramolecular C—H⋯N and C—H⋯O hydrogen bonds occur. In the crys...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051502/ https://www.ncbi.nlm.nih.gov/pubmed/21522869 http://dx.doi.org/10.1107/S160053681100136X |
Sumario: | In the title complex, [Co(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Co(II) ion is six-coordinated by the N,N′,N′′-tridentate Schiff base, the N atoms of two thiocyanate ligands and one water molecule in a distorted octahedral geometry. Intramolecular C—H⋯N and C—H⋯O hydrogen bonds occur. In the crystal, intermolecular O—H⋯O, O—H⋯S, C—H⋯S and S⋯S [3.5546 (18) Å] interactions result in an infinite three-dimensional network. |
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