Aqua­{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)cobalt(II)

In the title complex, [Co(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Co(II) ion is six-coordinated by the N,N′,N′′-tridentate Schiff base, the N atoms of two thio­cyanate ligands and one water mol­ecule in a distorted octa­hedral geometry. Intra­molecular C—H⋯N and C—H⋯O hydrogen bonds occur. In the crys...

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Detalles Bibliográficos
Autores principales: Suleiman Gwaram, Nura, Ikmal Hisham, Nurul Azimah, Khaledi, Hamid, Mohd Ali, Hapipah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051502/
https://www.ncbi.nlm.nih.gov/pubmed/21522869
http://dx.doi.org/10.1107/S160053681100136X
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author Suleiman Gwaram, Nura
Ikmal Hisham, Nurul Azimah
Khaledi, Hamid
Mohd Ali, Hapipah
author_facet Suleiman Gwaram, Nura
Ikmal Hisham, Nurul Azimah
Khaledi, Hamid
Mohd Ali, Hapipah
author_sort Suleiman Gwaram, Nura
collection PubMed
description In the title complex, [Co(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Co(II) ion is six-coordinated by the N,N′,N′′-tridentate Schiff base, the N atoms of two thio­cyanate ligands and one water mol­ecule in a distorted octa­hedral geometry. Intra­molecular C—H⋯N and C—H⋯O hydrogen bonds occur. In the crystal, inter­molecular O—H⋯O, O—H⋯S, C—H⋯S and S⋯S [3.5546 (18) Å] inter­actions result in an infinite three-dimensional network.
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spelling pubmed-30515022011-04-26 Aqua­{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)cobalt(II) Suleiman Gwaram, Nura Ikmal Hisham, Nurul Azimah Khaledi, Hamid Mohd Ali, Hapipah Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(NCS)(2)(C(13)H(19)N(3)O)(H(2)O)], the Co(II) ion is six-coordinated by the N,N′,N′′-tridentate Schiff base, the N atoms of two thio­cyanate ligands and one water mol­ecule in a distorted octa­hedral geometry. Intra­molecular C—H⋯N and C—H⋯O hydrogen bonds occur. In the crystal, inter­molecular O—H⋯O, O—H⋯S, C—H⋯S and S⋯S [3.5546 (18) Å] inter­actions result in an infinite three-dimensional network. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051502/ /pubmed/21522869 http://dx.doi.org/10.1107/S160053681100136X Text en © Suleiman Gwaram et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suleiman Gwaram, Nura
Ikmal Hisham, Nurul Azimah
Khaledi, Hamid
Mohd Ali, Hapipah
Aqua­{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)cobalt(II)
title Aqua­{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)cobalt(II)
title_full Aqua­{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)cobalt(II)
title_fullStr Aqua­{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)cobalt(II)
title_full_unstemmed Aqua­{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)cobalt(II)
title_short Aqua­{2-morpholino-N-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) N,N′,N′′}bis­(thio­cyanato-κN)cobalt(II)
title_sort aqua­{2-morpholino-n-[1-(2-pyrid­yl)ethyl­idene]ethanamine-κ(3) n,n′,n′′}bis­(thio­cyanato-κn)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051502/
https://www.ncbi.nlm.nih.gov/pubmed/21522869
http://dx.doi.org/10.1107/S160053681100136X
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