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N,N′-Dicyclohexyl-N′′,N′′-dimethylphosphoric triamide
In the title compound, C(14)H(30)N(3)OP, both cyclohexyl groups adopt chair conformations with the NH unit in an equatorial position. The P atom adopts a slightly distorted tetrahedral environment. In the (CH(3))(2)NP(O) unit, the O—P—N—C torsion angles, showing the orientations of the methyl grou...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051506/ https://www.ncbi.nlm.nih.gov/pubmed/21523155 http://dx.doi.org/10.1107/S160053681100287X |
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author | Sabbaghi, Fahimeh Pourayoubi, Mehrdad Karimi Ahmadabad, Fatemeh Azarkamanzad, Zahra Ebrahimi Valmoozi, Ali Asghar |
author_facet | Sabbaghi, Fahimeh Pourayoubi, Mehrdad Karimi Ahmadabad, Fatemeh Azarkamanzad, Zahra Ebrahimi Valmoozi, Ali Asghar |
author_sort | Sabbaghi, Fahimeh |
collection | PubMed |
description | In the title compound, C(14)H(30)N(3)OP, both cyclohexyl groups adopt chair conformations with the NH unit in an equatorial position. The P atom adopts a slightly distorted tetrahedral environment. In the (CH(3))(2)NP(O) unit, the O—P—N—C torsion angles, showing the orientations of the methyl groups with respect to the phosphoryl group, are −166.6 (3) and 34.6 (4)°. The O atom of the P=O group acts as a double hydrogen-bond acceptor and is involved in two different intermolecular N—H⋯OP hydrogen bonds, building R (2) (2)(8) rings that are further linked into chains running parallel to the b axis. |
format | Text |
id | pubmed-3051506 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30515062011-04-26 N,N′-Dicyclohexyl-N′′,N′′-dimethylphosphoric triamide Sabbaghi, Fahimeh Pourayoubi, Mehrdad Karimi Ahmadabad, Fatemeh Azarkamanzad, Zahra Ebrahimi Valmoozi, Ali Asghar Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(30)N(3)OP, both cyclohexyl groups adopt chair conformations with the NH unit in an equatorial position. The P atom adopts a slightly distorted tetrahedral environment. In the (CH(3))(2)NP(O) unit, the O—P—N—C torsion angles, showing the orientations of the methyl groups with respect to the phosphoryl group, are −166.6 (3) and 34.6 (4)°. The O atom of the P=O group acts as a double hydrogen-bond acceptor and is involved in two different intermolecular N—H⋯OP hydrogen bonds, building R (2) (2)(8) rings that are further linked into chains running parallel to the b axis. International Union of Crystallography 2011-01-26 /pmc/articles/PMC3051506/ /pubmed/21523155 http://dx.doi.org/10.1107/S160053681100287X Text en © Sabbaghi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sabbaghi, Fahimeh Pourayoubi, Mehrdad Karimi Ahmadabad, Fatemeh Azarkamanzad, Zahra Ebrahimi Valmoozi, Ali Asghar N,N′-Dicyclohexyl-N′′,N′′-dimethylphosphoric triamide |
title |
N,N′-Dicyclohexyl-N′′,N′′-dimethylphosphoric triamide |
title_full |
N,N′-Dicyclohexyl-N′′,N′′-dimethylphosphoric triamide |
title_fullStr |
N,N′-Dicyclohexyl-N′′,N′′-dimethylphosphoric triamide |
title_full_unstemmed |
N,N′-Dicyclohexyl-N′′,N′′-dimethylphosphoric triamide |
title_short |
N,N′-Dicyclohexyl-N′′,N′′-dimethylphosphoric triamide |
title_sort | n,n′-dicyclohexyl-n′′,n′′-dimethylphosphoric triamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051506/ https://www.ncbi.nlm.nih.gov/pubmed/21523155 http://dx.doi.org/10.1107/S160053681100287X |
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