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N,N′-Dicyclo­hexyl-N′′,N′′-dimethyl­phospho­ric triamide

In the title compound, C(14)H(30)N(3)OP, both cyclo­hexyl groups adopt chair conformations with the NH unit in an equatorial position. The P atom adopts a slightly distorted tetra­hedral environment. In the (CH(3))(2)NP(O) unit, the O—P—N—C torsion angles, showing the orientations of the methyl grou...

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Autores principales: Sabbaghi, Fahimeh, Pourayoubi, Mehrdad, Karimi Ahmadabad, Fatemeh, Azarkamanzad, Zahra, Ebrahimi Valmoozi, Ali Asghar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051506/
https://www.ncbi.nlm.nih.gov/pubmed/21523155
http://dx.doi.org/10.1107/S160053681100287X
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author Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Karimi Ahmadabad, Fatemeh
Azarkamanzad, Zahra
Ebrahimi Valmoozi, Ali Asghar
author_facet Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Karimi Ahmadabad, Fatemeh
Azarkamanzad, Zahra
Ebrahimi Valmoozi, Ali Asghar
author_sort Sabbaghi, Fahimeh
collection PubMed
description In the title compound, C(14)H(30)N(3)OP, both cyclo­hexyl groups adopt chair conformations with the NH unit in an equatorial position. The P atom adopts a slightly distorted tetra­hedral environment. In the (CH(3))(2)NP(O) unit, the O—P—N—C torsion angles, showing the orientations of the methyl groups with respect to the phosphoryl group, are −166.6 (3) and 34.6 (4)°. The O atom of the P=O group acts as a double hydrogen-bond acceptor and is involved in two different inter­molecular N—H⋯OP hydrogen bonds, building R (2) (2)(8) rings that are further linked into chains running parallel to the b axis.
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spelling pubmed-30515062011-04-26 N,N′-Dicyclo­hexyl-N′′,N′′-dimethyl­phospho­ric triamide Sabbaghi, Fahimeh Pourayoubi, Mehrdad Karimi Ahmadabad, Fatemeh Azarkamanzad, Zahra Ebrahimi Valmoozi, Ali Asghar Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(30)N(3)OP, both cyclo­hexyl groups adopt chair conformations with the NH unit in an equatorial position. The P atom adopts a slightly distorted tetra­hedral environment. In the (CH(3))(2)NP(O) unit, the O—P—N—C torsion angles, showing the orientations of the methyl groups with respect to the phosphoryl group, are −166.6 (3) and 34.6 (4)°. The O atom of the P=O group acts as a double hydrogen-bond acceptor and is involved in two different inter­molecular N—H⋯OP hydrogen bonds, building R (2) (2)(8) rings that are further linked into chains running parallel to the b axis. International Union of Crystallography 2011-01-26 /pmc/articles/PMC3051506/ /pubmed/21523155 http://dx.doi.org/10.1107/S160053681100287X Text en © Sabbaghi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sabbaghi, Fahimeh
Pourayoubi, Mehrdad
Karimi Ahmadabad, Fatemeh
Azarkamanzad, Zahra
Ebrahimi Valmoozi, Ali Asghar
N,N′-Dicyclo­hexyl-N′′,N′′-dimethyl­phospho­ric triamide
title N,N′-Dicyclo­hexyl-N′′,N′′-dimethyl­phospho­ric triamide
title_full N,N′-Dicyclo­hexyl-N′′,N′′-dimethyl­phospho­ric triamide
title_fullStr N,N′-Dicyclo­hexyl-N′′,N′′-dimethyl­phospho­ric triamide
title_full_unstemmed N,N′-Dicyclo­hexyl-N′′,N′′-dimethyl­phospho­ric triamide
title_short N,N′-Dicyclo­hexyl-N′′,N′′-dimethyl­phospho­ric triamide
title_sort n,n′-dicyclo­hexyl-n′′,n′′-dimethyl­phospho­ric triamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051506/
https://www.ncbi.nlm.nih.gov/pubmed/21523155
http://dx.doi.org/10.1107/S160053681100287X
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