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[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate
In the title compound, [Ru(3)(C(29)H(30)P(2))(C(19)H(17)PS)(CO)(9)]·0.25CH(2)Cl(2), the atoms of the dichloromethane solvent molecule have a fractional site occupancy of 0.25; the dichloromethane molecule is disordered about an inversion centre. The bis(di-o-tolylphosphanyl)methane ligand bri...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051507/ https://www.ncbi.nlm.nih.gov/pubmed/21522863 http://dx.doi.org/10.1107/S160053681100081X |
Sumario: | In the title compound, [Ru(3)(C(29)H(30)P(2))(C(19)H(17)PS)(CO)(9)]·0.25CH(2)Cl(2), the atoms of the dichloromethane solvent molecule have a fractional site occupancy of 0.25; the dichloromethane molecule is disordered about an inversion centre. The bis(di-o-tolylphosphanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom; its S-bonded phenyl ring is disordered over two orientations in a 0.53 (4):0.47 (4) ratio. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings attached to each P atom of the diphenylphosphanyl ligand are 68.4 (2) and 71.5 (2)°. In the crystal, molecules are linked into [001] chains via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions also occur. |
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