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[μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphane-3κP]-triangulo-triruthenium(0) dichloro­methane 0.25-solvate

In the title compound, [Ru(3)(C(29)H(30)P(2))(C(19)H(17)PS)(CO)(9)]·0.25CH(2)Cl(2), the atoms of the dichloro­methane solvent mol­ecule have a fractional site occupancy of 0.25; the dichloro­methane mol­ecule is disordered about an inversion centre. The bis­(di-o-tolyl­phosphan­yl)methane ligand bri...

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Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Hafiz Malik, H. A., Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051507/
https://www.ncbi.nlm.nih.gov/pubmed/21522863
http://dx.doi.org/10.1107/S160053681100081X
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author Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Hafiz Malik, H. A.
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Hafiz Malik, H. A.
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Shawkataly, Omar bin
collection PubMed
description In the title compound, [Ru(3)(C(29)H(30)P(2))(C(19)H(17)PS)(CO)(9)]·0.25CH(2)Cl(2), the atoms of the dichloro­methane solvent mol­ecule have a fractional site occupancy of 0.25; the dichloro­methane mol­ecule is disordered about an inversion centre. The bis­(di-o-tolyl­phosphan­yl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom; its S-bonded phenyl ring is disordered over two orientations in a 0.53 (4):0.47 (4) ratio. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings attached to each P atom of the diphenyl­phosphanyl ligand are 68.4 (2) and 71.5 (2)°. In the crystal, mol­ecules are linked into [001] chains via inter­molecular C—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯π inter­actions also occur.
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spelling pubmed-30515072011-04-26 [μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphane-3κP]-triangulo-triruthenium(0) dichloro­methane 0.25-solvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(3)(C(29)H(30)P(2))(C(19)H(17)PS)(CO)(9)]·0.25CH(2)Cl(2), the atoms of the dichloro­methane solvent mol­ecule have a fractional site occupancy of 0.25; the dichloro­methane mol­ecule is disordered about an inversion centre. The bis­(di-o-tolyl­phosphan­yl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom; its S-bonded phenyl ring is disordered over two orientations in a 0.53 (4):0.47 (4) ratio. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings attached to each P atom of the diphenyl­phosphanyl ligand are 68.4 (2) and 71.5 (2)°. In the crystal, mol­ecules are linked into [001] chains via inter­molecular C—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯π inter­actions also occur. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051507/ /pubmed/21522863 http://dx.doi.org/10.1107/S160053681100081X Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Hafiz Malik, H. A.
Yeap, Chin Sing
Fun, Hoong-Kun
[μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphane-3κP]-triangulo-triruthenium(0) dichloro­methane 0.25-solvate
title [μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphane-3κP]-triangulo-triruthenium(0) dichloro­methane 0.25-solvate
title_full [μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphane-3κP]-triangulo-triruthenium(0) dichloro­methane 0.25-solvate
title_fullStr [μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphane-3κP]-triangulo-triruthenium(0) dichloro­methane 0.25-solvate
title_full_unstemmed [μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphane-3κP]-triangulo-triruthenium(0) dichloro­methane 0.25-solvate
title_short [μ-Bis(di-o-tolyl­phosphan­yl)methane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphen­yl(phenyl­sulfanylmeth­yl)phosphane-3κP]-triangulo-triruthenium(0) dichloro­methane 0.25-solvate
title_sort [μ-bis(di-o-tolyl­phosphan­yl)methane-1:2κ(2) p:p′]nona­carbonyl-1κ(3) c,2κ(3) c,3κ(3) c-[diphen­yl(phenyl­sulfanylmeth­yl)phosphane-3κp]-triangulo-triruthenium(0) dichloro­methane 0.25-solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051507/
https://www.ncbi.nlm.nih.gov/pubmed/21522863
http://dx.doi.org/10.1107/S160053681100081X
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