Cargando…
[μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate
In the title compound, [Ru(3)(C(29)H(30)P(2))(C(19)H(17)PS)(CO)(9)]·0.25CH(2)Cl(2), the atoms of the dichloromethane solvent molecule have a fractional site occupancy of 0.25; the dichloromethane molecule is disordered about an inversion centre. The bis(di-o-tolylphosphanyl)methane ligand bri...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051507/ https://www.ncbi.nlm.nih.gov/pubmed/21522863 http://dx.doi.org/10.1107/S160053681100081X |
_version_ | 1782199495407173632 |
---|---|
author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Shawkataly, Omar bin |
collection | PubMed |
description | In the title compound, [Ru(3)(C(29)H(30)P(2))(C(19)H(17)PS)(CO)(9)]·0.25CH(2)Cl(2), the atoms of the dichloromethane solvent molecule have a fractional site occupancy of 0.25; the dichloromethane molecule is disordered about an inversion centre. The bis(di-o-tolylphosphanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom; its S-bonded phenyl ring is disordered over two orientations in a 0.53 (4):0.47 (4) ratio. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings attached to each P atom of the diphenylphosphanyl ligand are 68.4 (2) and 71.5 (2)°. In the crystal, molecules are linked into [001] chains via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions also occur. |
format | Text |
id | pubmed-3051507 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30515072011-04-26 [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ru(3)(C(29)H(30)P(2))(C(19)H(17)PS)(CO)(9)]·0.25CH(2)Cl(2), the atoms of the dichloromethane solvent molecule have a fractional site occupancy of 0.25; the dichloromethane molecule is disordered about an inversion centre. The bis(di-o-tolylphosphanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom; its S-bonded phenyl ring is disordered over two orientations in a 0.53 (4):0.47 (4) ratio. All the P atoms are equatorial with respect to the Ru(3) triangle: each Ru atom also bears one equatorial and two axial terminal carbonyl ligands. The dihedral angles between the two benzene rings attached to each P atom of the diphenylphosphanyl ligand are 68.4 (2) and 71.5 (2)°. In the crystal, molecules are linked into [001] chains via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions also occur. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051507/ /pubmed/21522863 http://dx.doi.org/10.1107/S160053681100081X Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
title | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
title_full | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
title_fullStr | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
title_full_unstemmed | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
title_short | [μ-Bis(di-o-tolylphosphanyl)methane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[diphenyl(phenylsulfanylmethyl)phosphane-3κP]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
title_sort | [μ-bis(di-o-tolylphosphanyl)methane-1:2κ(2)
p:p′]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-[diphenyl(phenylsulfanylmethyl)phosphane-3κp]-triangulo-triruthenium(0) dichloromethane 0.25-solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051507/ https://www.ncbi.nlm.nih.gov/pubmed/21522863 http://dx.doi.org/10.1107/S160053681100081X |
work_keys_str_mv | AT shawkatalyomarbin mbisdiotolylphosphanylmethane12k2ppnonacarbonyl1k3c2k3c3k3cdiphenylphenylsulfanylmethylphosphane3kptriangulotriruthenium0dichloromethane025solvate AT khanimthyazahmed mbisdiotolylphosphanylmethane12k2ppnonacarbonyl1k3c2k3c3k3cdiphenylphenylsulfanylmethylphosphane3kptriangulotriruthenium0dichloromethane025solvate AT hafizmalikha mbisdiotolylphosphanylmethane12k2ppnonacarbonyl1k3c2k3c3k3cdiphenylphenylsulfanylmethylphosphane3kptriangulotriruthenium0dichloromethane025solvate AT yeapchinsing mbisdiotolylphosphanylmethane12k2ppnonacarbonyl1k3c2k3c3k3cdiphenylphenylsulfanylmethylphosphane3kptriangulotriruthenium0dichloromethane025solvate AT funhoongkun mbisdiotolylphosphanylmethane12k2ppnonacarbonyl1k3c2k3c3k3cdiphenylphenylsulfanylmethylphosphane3kptriangulotriruthenium0dichloromethane025solvate |