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Acetonitrile{3-[bis(2-pyridylmethyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate
In the title compound, [Cu(ClO(4))(C(2)H(3)N)(C(15)H(19)N(3)O)]ClO(4), the Cu(II) ion is coordinated by three N atoms and a hydroxyl-O atom of the tetradentate ligand, an O atom of a perchlorate ion and an N atom of an acetonitrile ligand giving a tetragonally distorted octahedral environment aro...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051508/ https://www.ncbi.nlm.nih.gov/pubmed/21522828 http://dx.doi.org/10.1107/S1600536810053985 |
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author | Shin, Jong Won Rowthu, Sankara Rao Cho, Hyun Jung Min, Kil Sik |
author_facet | Shin, Jong Won Rowthu, Sankara Rao Cho, Hyun Jung Min, Kil Sik |
author_sort | Shin, Jong Won |
collection | PubMed |
description | In the title compound, [Cu(ClO(4))(C(2)H(3)N)(C(15)H(19)N(3)O)]ClO(4), the Cu(II) ion is coordinated by three N atoms and a hydroxyl-O atom of the tetradentate ligand, an O atom of a perchlorate ion and an N atom of an acetonitrile ligand giving a tetragonally distorted octahedral environment around the copper(II) atom. There is an offset inter-complex face-to-face π–π interaction [centroid–centroid distance = 3.718 (2) Å] involving one of the pyridine rings of the ligand as well as an intra-complex O—H⋯O hydrogen-bonding interaction between the coordinated hydroxyl group of the ligand and the perchlorate counter-ion. |
format | Text |
id | pubmed-3051508 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30515082011-04-26 Acetonitrile{3-[bis(2-pyridylmethyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate Shin, Jong Won Rowthu, Sankara Rao Cho, Hyun Jung Min, Kil Sik Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(ClO(4))(C(2)H(3)N)(C(15)H(19)N(3)O)]ClO(4), the Cu(II) ion is coordinated by three N atoms and a hydroxyl-O atom of the tetradentate ligand, an O atom of a perchlorate ion and an N atom of an acetonitrile ligand giving a tetragonally distorted octahedral environment around the copper(II) atom. There is an offset inter-complex face-to-face π–π interaction [centroid–centroid distance = 3.718 (2) Å] involving one of the pyridine rings of the ligand as well as an intra-complex O—H⋯O hydrogen-bonding interaction between the coordinated hydroxyl group of the ligand and the perchlorate counter-ion. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051508/ /pubmed/21522828 http://dx.doi.org/10.1107/S1600536810053985 Text en © Shin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shin, Jong Won Rowthu, Sankara Rao Cho, Hyun Jung Min, Kil Sik Acetonitrile{3-[bis(2-pyridylmethyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate |
title | Acetonitrile{3-[bis(2-pyridylmethyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate |
title_full | Acetonitrile{3-[bis(2-pyridylmethyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate |
title_fullStr | Acetonitrile{3-[bis(2-pyridylmethyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate |
title_full_unstemmed | Acetonitrile{3-[bis(2-pyridylmethyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate |
title_short | Acetonitrile{3-[bis(2-pyridylmethyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate |
title_sort | acetonitrile{3-[bis(2-pyridylmethyl-κn)amino-κn]propanol-κo}(perchlorato-κo)copper(ii) perchlorate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051508/ https://www.ncbi.nlm.nih.gov/pubmed/21522828 http://dx.doi.org/10.1107/S1600536810053985 |
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