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Acetonitrile­{3-[bis­(2-pyridyl­methyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate

In the title compound, [Cu(ClO(4))(C(2)H(3)N)(C(15)H(19)N(3)O)]ClO(4), the Cu(II) ion is coordinated by three N atoms and a hydroxyl-O atom of the tetra­dentate ligand, an O atom of a perchlorate ion and an N atom of an acetonitrile ligand giving a tetra­gonally distorted octa­hedral environment aro...

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Detalles Bibliográficos
Autores principales: Shin, Jong Won, Rowthu, Sankara Rao, Cho, Hyun Jung, Min, Kil Sik
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051508/
https://www.ncbi.nlm.nih.gov/pubmed/21522828
http://dx.doi.org/10.1107/S1600536810053985
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author Shin, Jong Won
Rowthu, Sankara Rao
Cho, Hyun Jung
Min, Kil Sik
author_facet Shin, Jong Won
Rowthu, Sankara Rao
Cho, Hyun Jung
Min, Kil Sik
author_sort Shin, Jong Won
collection PubMed
description In the title compound, [Cu(ClO(4))(C(2)H(3)N)(C(15)H(19)N(3)O)]ClO(4), the Cu(II) ion is coordinated by three N atoms and a hydroxyl-O atom of the tetra­dentate ligand, an O atom of a perchlorate ion and an N atom of an acetonitrile ligand giving a tetra­gonally distorted octa­hedral environment around the copper(II) atom. There is an offset inter-complex face-to-face π–π inter­action [centroid–centroid distance = 3.718 (2) Å] involving one of the pyridine rings of the ligand as well as an intra-complex O—H⋯O hydrogen-bonding inter­action between the coordinated hydroxyl group of the ligand and the perchlorate counter-ion.
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spelling pubmed-30515082011-04-26 Acetonitrile­{3-[bis­(2-pyridyl­methyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate Shin, Jong Won Rowthu, Sankara Rao Cho, Hyun Jung Min, Kil Sik Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(ClO(4))(C(2)H(3)N)(C(15)H(19)N(3)O)]ClO(4), the Cu(II) ion is coordinated by three N atoms and a hydroxyl-O atom of the tetra­dentate ligand, an O atom of a perchlorate ion and an N atom of an acetonitrile ligand giving a tetra­gonally distorted octa­hedral environment around the copper(II) atom. There is an offset inter-complex face-to-face π–π inter­action [centroid–centroid distance = 3.718 (2) Å] involving one of the pyridine rings of the ligand as well as an intra-complex O—H⋯O hydrogen-bonding inter­action between the coordinated hydroxyl group of the ligand and the perchlorate counter-ion. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051508/ /pubmed/21522828 http://dx.doi.org/10.1107/S1600536810053985 Text en © Shin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shin, Jong Won
Rowthu, Sankara Rao
Cho, Hyun Jung
Min, Kil Sik
Acetonitrile­{3-[bis­(2-pyridyl­methyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate
title Acetonitrile­{3-[bis­(2-pyridyl­methyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate
title_full Acetonitrile­{3-[bis­(2-pyridyl­methyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate
title_fullStr Acetonitrile­{3-[bis­(2-pyridyl­methyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate
title_full_unstemmed Acetonitrile­{3-[bis­(2-pyridyl­methyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate
title_short Acetonitrile­{3-[bis­(2-pyridyl­methyl-κN)amino-κN]propanol-κO}(perchlorato-κO)copper(II) perchlorate
title_sort acetonitrile­{3-[bis­(2-pyridyl­methyl-κn)amino-κn]propanol-κo}(perchlorato-κo)copper(ii) perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051508/
https://www.ncbi.nlm.nih.gov/pubmed/21522828
http://dx.doi.org/10.1107/S1600536810053985
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AT chohyunjung acetonitrile3bis2pyridylmethylknaminoknpropanolkoperchloratokocopperiiperchlorate
AT minkilsik acetonitrile3bis2pyridylmethylknaminoknpropanolkoperchloratokocopperiiperchlorate