Acridinium 6-carb­oxy­pyridine-2-carboxyl­ate monohydrate

The title compound, C(13)H(10)N(+)·C(7)H(4)NO(4) (−)·H(2)O or (acrH)(+)(pydcH)(−)·H(2)O, is a monohydrate of acridinium cations and a mono-deprotonated pyridine-2,6-dicarb­oxy­lic acid. The structure contains a range of non-covalent inter­actions, such as O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, as we...

Descripción completa

Detalles Bibliográficos
Autores principales: Derikvand, Zohreh, Olmstead, Marilyn M., Attar Gharamaleki, Jafar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051510/
https://www.ncbi.nlm.nih.gov/pubmed/21523086
http://dx.doi.org/10.1107/S1600536810053791
Descripción
Sumario:The title compound, C(13)H(10)N(+)·C(7)H(4)NO(4) (−)·H(2)O or (acrH)(+)(pydcH)(−)·H(2)O, is a monohydrate of acridinium cations and a mono-deprotonated pyridine-2,6-dicarb­oxy­lic acid. The structure contains a range of non-covalent inter­actions, such as O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, as well as π–π stacking [range of centroid–centroid distances = 3.4783 (5)–3.8059 (5) Å]. The N—H⋯O hydrogen bond between the donor acridinium cation and the carboxyl­ate acceptor is particularly strong. The average separation between the π-stacked acridinium planes is 3.42 (3) Å.

Ejemplares similares