Acridinium 6-carb­oxy­pyridine-2-carboxyl­ate monohydrate

The title compound, C(13)H(10)N(+)·C(7)H(4)NO(4) (−)·H(2)O or (acrH)(+)(pydcH)(−)·H(2)O, is a monohydrate of acridinium cations and a mono-deprotonated pyridine-2,6-dicarb­oxy­lic acid. The structure contains a range of non-covalent inter­actions, such as O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, as we...

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Detalles Bibliográficos
Autores principales: Derikvand, Zohreh, Olmstead, Marilyn M., Attar Gharamaleki, Jafar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051510/
https://www.ncbi.nlm.nih.gov/pubmed/21523086
http://dx.doi.org/10.1107/S1600536810053791
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author Derikvand, Zohreh
Olmstead, Marilyn M.
Attar Gharamaleki, Jafar
author_facet Derikvand, Zohreh
Olmstead, Marilyn M.
Attar Gharamaleki, Jafar
author_sort Derikvand, Zohreh
collection PubMed
description The title compound, C(13)H(10)N(+)·C(7)H(4)NO(4) (−)·H(2)O or (acrH)(+)(pydcH)(−)·H(2)O, is a monohydrate of acridinium cations and a mono-deprotonated pyridine-2,6-dicarb­oxy­lic acid. The structure contains a range of non-covalent inter­actions, such as O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, as well as π–π stacking [range of centroid–centroid distances = 3.4783 (5)–3.8059 (5) Å]. The N—H⋯O hydrogen bond between the donor acridinium cation and the carboxyl­ate acceptor is particularly strong. The average separation between the π-stacked acridinium planes is 3.42 (3) Å.
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spelling pubmed-30515102011-04-26 Acridinium 6-carb­oxy­pyridine-2-carboxyl­ate monohydrate Derikvand, Zohreh Olmstead, Marilyn M. Attar Gharamaleki, Jafar Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(10)N(+)·C(7)H(4)NO(4) (−)·H(2)O or (acrH)(+)(pydcH)(−)·H(2)O, is a monohydrate of acridinium cations and a mono-deprotonated pyridine-2,6-dicarb­oxy­lic acid. The structure contains a range of non-covalent inter­actions, such as O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds, as well as π–π stacking [range of centroid–centroid distances = 3.4783 (5)–3.8059 (5) Å]. The N—H⋯O hydrogen bond between the donor acridinium cation and the carboxyl­ate acceptor is particularly strong. The average separation between the π-stacked acridinium planes is 3.42 (3) Å. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051510/ /pubmed/21523086 http://dx.doi.org/10.1107/S1600536810053791 Text en © Derikvand et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Derikvand, Zohreh
Olmstead, Marilyn M.
Attar Gharamaleki, Jafar
Acridinium 6-carb­oxy­pyridine-2-carboxyl­ate monohydrate
title Acridinium 6-carb­oxy­pyridine-2-carboxyl­ate monohydrate
title_full Acridinium 6-carb­oxy­pyridine-2-carboxyl­ate monohydrate
title_fullStr Acridinium 6-carb­oxy­pyridine-2-carboxyl­ate monohydrate
title_full_unstemmed Acridinium 6-carb­oxy­pyridine-2-carboxyl­ate monohydrate
title_short Acridinium 6-carb­oxy­pyridine-2-carboxyl­ate monohydrate
title_sort acridinium 6-carb­oxy­pyridine-2-carboxyl­ate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051510/
https://www.ncbi.nlm.nih.gov/pubmed/21523086
http://dx.doi.org/10.1107/S1600536810053791
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AT olmsteadmarilynm acridinium6carboxypyridine2carboxylatemonohydrate
AT attargharamalekijafar acridinium6carboxypyridine2carboxylatemonohydrate

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