N-(4-Chloro­butano­yl)-N′-phenyl­thio­urea

The asymmetric unit of the title compound, C(11)H(13)ClN(2)OS, contains two independent mol­ecules. Both mol­ecules maintain a trans–cis configuration with respect to the position of the carbonyl group and the benzene ring against the thione group across the C—N bonds. The mol­ecules are stabilized...

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Detalles Bibliográficos
Autores principales: Yamin, Bohari M., Othman, Nur Eliyanti Ali, Yusof, M. Sukeri M., Embong, Farhana.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051517/
https://www.ncbi.nlm.nih.gov/pubmed/21523089
http://dx.doi.org/10.1107/S1600536811001498
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author Yamin, Bohari M.
Othman, Nur Eliyanti Ali
Yusof, M. Sukeri M.
Embong, Farhana.
author_facet Yamin, Bohari M.
Othman, Nur Eliyanti Ali
Yusof, M. Sukeri M.
Embong, Farhana.
author_sort Yamin, Bohari M.
collection PubMed
description The asymmetric unit of the title compound, C(11)H(13)ClN(2)OS, contains two independent mol­ecules. Both mol­ecules maintain a trans–cis configuration with respect to the position of the carbonyl group and the benzene ring against the thione group across the C—N bonds. The mol­ecules are stabilized by intra­molecular N—H⋯O hydrogen bonds. In the crystal, the mol­ecules are linked by inter­molecular N—H⋯S, N—H⋯O and C—H⋯S hydrogen bonds into chains along the c axis. C—H⋯π inter­actions further stabilize the crystal structure.
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spelling pubmed-30515172011-04-26 N-(4-Chloro­butano­yl)-N′-phenyl­thio­urea Yamin, Bohari M. Othman, Nur Eliyanti Ali Yusof, M. Sukeri M. Embong, Farhana. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(11)H(13)ClN(2)OS, contains two independent mol­ecules. Both mol­ecules maintain a trans–cis configuration with respect to the position of the carbonyl group and the benzene ring against the thione group across the C—N bonds. The mol­ecules are stabilized by intra­molecular N—H⋯O hydrogen bonds. In the crystal, the mol­ecules are linked by inter­molecular N—H⋯S, N—H⋯O and C—H⋯S hydrogen bonds into chains along the c axis. C—H⋯π inter­actions further stabilize the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051517/ /pubmed/21523089 http://dx.doi.org/10.1107/S1600536811001498 Text en © Yamin et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yamin, Bohari M.
Othman, Nur Eliyanti Ali
Yusof, M. Sukeri M.
Embong, Farhana.
N-(4-Chloro­butano­yl)-N′-phenyl­thio­urea
title N-(4-Chloro­butano­yl)-N′-phenyl­thio­urea
title_full N-(4-Chloro­butano­yl)-N′-phenyl­thio­urea
title_fullStr N-(4-Chloro­butano­yl)-N′-phenyl­thio­urea
title_full_unstemmed N-(4-Chloro­butano­yl)-N′-phenyl­thio­urea
title_short N-(4-Chloro­butano­yl)-N′-phenyl­thio­urea
title_sort n-(4-chloro­butano­yl)-n′-phenyl­thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051517/
https://www.ncbi.nlm.nih.gov/pubmed/21523089
http://dx.doi.org/10.1107/S1600536811001498
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AT yusofmsukerim n4chlorobutanoylnphenylthiourea
AT embongfarhana n4chlorobutanoylnphenylthiourea

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