Ethyl 1-benzene­sulfonyl-2-[(E)-2-(2-methyl­phen­yl)ethen­yl]indole-3-carboxyl­ate

In the title compound, C(26)H(23)NO(4)S, the phenyl, tolyl and ester groups make dihedral angles of 82.28 (5), 77.67 (6) and 8.52 (6)°, respectively, with the indole ring system. The S atom of the sulfonyl group is displaced by 0.1968 (4) Å from the indole mean plane. The mol­ecular structure is sta...

Descripción completa

Detalles Bibliográficos
Autores principales: Ramathilagam, C., Saravanan, V., Mohanakrishnan, A. K., Chakkaravarthi, G., Umarani, P. R., Manivannan, V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051518/
https://www.ncbi.nlm.nih.gov/pubmed/21523111
http://dx.doi.org/10.1107/S1600536811001863
_version_ 1782199498062168064
author Ramathilagam, C.
Saravanan, V.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
Umarani, P. R.
Manivannan, V.
author_facet Ramathilagam, C.
Saravanan, V.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
Umarani, P. R.
Manivannan, V.
author_sort Ramathilagam, C.
collection PubMed
description In the title compound, C(26)H(23)NO(4)S, the phenyl, tolyl and ester groups make dihedral angles of 82.28 (5), 77.67 (6) and 8.52 (6)°, respectively, with the indole ring system. The S atom of the sulfonyl group is displaced by 0.1968 (4) Å from the indole mean plane. The mol­ecular structure is stabilized by weak intra­molecular C—H⋯O inter­actions. The crystal structure structure features short intramolecular C—H⋯O contacts and π–π stacking inter­actions between the phenyl and tolyl groups [centroid–centroid distance = 3.9448 (11) Å].
format Text
id pubmed-3051518
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30515182011-04-26 Ethyl 1-benzene­sulfonyl-2-[(E)-2-(2-methyl­phen­yl)ethen­yl]indole-3-carboxyl­ate Ramathilagam, C. Saravanan, V. Mohanakrishnan, A. K. Chakkaravarthi, G. Umarani, P. R. Manivannan, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(23)NO(4)S, the phenyl, tolyl and ester groups make dihedral angles of 82.28 (5), 77.67 (6) and 8.52 (6)°, respectively, with the indole ring system. The S atom of the sulfonyl group is displaced by 0.1968 (4) Å from the indole mean plane. The mol­ecular structure is stabilized by weak intra­molecular C—H⋯O inter­actions. The crystal structure structure features short intramolecular C—H⋯O contacts and π–π stacking inter­actions between the phenyl and tolyl groups [centroid–centroid distance = 3.9448 (11) Å]. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051518/ /pubmed/21523111 http://dx.doi.org/10.1107/S1600536811001863 Text en © Ramathilagam et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ramathilagam, C.
Saravanan, V.
Mohanakrishnan, A. K.
Chakkaravarthi, G.
Umarani, P. R.
Manivannan, V.
Ethyl 1-benzene­sulfonyl-2-[(E)-2-(2-methyl­phen­yl)ethen­yl]indole-3-carboxyl­ate
title Ethyl 1-benzene­sulfonyl-2-[(E)-2-(2-methyl­phen­yl)ethen­yl]indole-3-carboxyl­ate
title_full Ethyl 1-benzene­sulfonyl-2-[(E)-2-(2-methyl­phen­yl)ethen­yl]indole-3-carboxyl­ate
title_fullStr Ethyl 1-benzene­sulfonyl-2-[(E)-2-(2-methyl­phen­yl)ethen­yl]indole-3-carboxyl­ate
title_full_unstemmed Ethyl 1-benzene­sulfonyl-2-[(E)-2-(2-methyl­phen­yl)ethen­yl]indole-3-carboxyl­ate
title_short Ethyl 1-benzene­sulfonyl-2-[(E)-2-(2-methyl­phen­yl)ethen­yl]indole-3-carboxyl­ate
title_sort ethyl 1-benzene­sulfonyl-2-[(e)-2-(2-methyl­phen­yl)ethen­yl]indole-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051518/
https://www.ncbi.nlm.nih.gov/pubmed/21523111
http://dx.doi.org/10.1107/S1600536811001863
work_keys_str_mv AT ramathilagamc ethyl1benzenesulfonyl2e22methylphenylethenylindole3carboxylate
AT saravananv ethyl1benzenesulfonyl2e22methylphenylethenylindole3carboxylate
AT mohanakrishnanak ethyl1benzenesulfonyl2e22methylphenylethenylindole3carboxylate
AT chakkaravarthig ethyl1benzenesulfonyl2e22methylphenylethenylindole3carboxylate
AT umaranipr ethyl1benzenesulfonyl2e22methylphenylethenylindole3carboxylate
AT manivannanv ethyl1benzenesulfonyl2e22methylphenylethenylindole3carboxylate

Ejemplares similares