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catena-Poly[[aquabis[2-(3-benzoylphenyl)propanoato-κ(2) O (1),O (1′)]cadmium(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
The 4,4′-bipyridine heterocycle in the polymeric title compound, [Cd(C(16)H(13)O(3))(2)(C(10)H(8)N(2))(H(2)O)](n), links adjacent Cd(II) ions into a chain running along the c axis. The Cd atom, which lies on a twofold rotation axis, is chelated by the carboxylate unit and exists in a seven-coordina...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051519/ https://www.ncbi.nlm.nih.gov/pubmed/21522872 http://dx.doi.org/10.1107/S1600536811001280 |
Sumario: | The 4,4′-bipyridine heterocycle in the polymeric title compound, [Cd(C(16)H(13)O(3))(2)(C(10)H(8)N(2))(H(2)O)](n), links adjacent Cd(II) ions into a chain running along the c axis. The Cd atom, which lies on a twofold rotation axis, is chelated by the carboxylate unit and exists in a seven-coordinate pentagonal–bipyramidal geometry. The apical sites are occupied by N atoms. The water molecule also lies on the twofold rotation axis. The methyl substituent of the propanoate group is disordered over two positions in a 1:1 ratio. O—H⋯O hydrogen bonding between water molecules and adjacent carboxylate O atoms is observed. |
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