(2,2′-Bipyridine-κ(2) N,N′)bromido(1,4,7-trithia­cyclo­nonane-κ(3) S,S′,S′′)ruthenium(II) hexa­fluoridophosphate

The title compound, [RuBr(C(10)H(8)N(2))(C(6)H(12)S(3))]PF(6) or [RuBr(bpy)([9]aneS(3))]PF(6) ([9]aneS(3) is 1,4,7-trithia­cyclo­nonane and bpy is 2,2′-bipyridine), exhibits a very similar octahedral coordination geometry for the Ru(2+) atom to that of its [RuCl(bpy)([9]aneS(3))](+) analogue, with o...

Descripción completa

Detalles Bibliográficos
Autores principales: Fernandes, José A., Almeida Paz, Filipe A., Ramos, Ana I., Santos, Teresa M., Braga, Susana S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051521/
https://www.ncbi.nlm.nih.gov/pubmed/21522914
http://dx.doi.org/10.1107/S1600536811002662
Descripción
Sumario:The title compound, [RuBr(C(10)H(8)N(2))(C(6)H(12)S(3))]PF(6) or [RuBr(bpy)([9]aneS(3))]PF(6) ([9]aneS(3) is 1,4,7-trithia­cyclo­nonane and bpy is 2,2′-bipyridine), exhibits a very similar octahedral coordination geometry for the Ru(2+) atom to that of its [RuCl(bpy)([9]aneS(3))](+) analogue, with only the chloride ligand being substituted by a bromide ligand. The presence of a PF(6) (−) anion (alongside with the coordinated bromide ligand) promotes the existence of an extensive network of weak C—H⋯X (X = F, Br) inter­actions.

Ejemplares similares