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(2,2′-Bipyridine-κ(2) N,N′)bromido(1,4,7-trithiacyclononane-κ(3) S,S′,S′′)ruthenium(II) hexafluoridophosphate
The title compound, [RuBr(C(10)H(8)N(2))(C(6)H(12)S(3))]PF(6) or [RuBr(bpy)([9]aneS(3))]PF(6) ([9]aneS(3) is 1,4,7-trithiacyclononane and bpy is 2,2′-bipyridine), exhibits a very similar octahedral coordination geometry for the Ru(2+) atom to that of its [RuCl(bpy)([9]aneS(3))](+) analogue, with o...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2011
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051521/ https://www.ncbi.nlm.nih.gov/pubmed/21522914 http://dx.doi.org/10.1107/S1600536811002662 |
| _version_ | 1782199498886348800 |
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| author | Fernandes, José A. Almeida Paz, Filipe A. Ramos, Ana I. Santos, Teresa M. Braga, Susana S. |
| author_facet | Fernandes, José A. Almeida Paz, Filipe A. Ramos, Ana I. Santos, Teresa M. Braga, Susana S. |
| author_sort | Fernandes, José A. |
| collection | PubMed |
| description | The title compound, [RuBr(C(10)H(8)N(2))(C(6)H(12)S(3))]PF(6) or [RuBr(bpy)([9]aneS(3))]PF(6) ([9]aneS(3) is 1,4,7-trithiacyclononane and bpy is 2,2′-bipyridine), exhibits a very similar octahedral coordination geometry for the Ru(2+) atom to that of its [RuCl(bpy)([9]aneS(3))](+) analogue, with only the chloride ligand being substituted by a bromide ligand. The presence of a PF(6) (−) anion (alongside with the coordinated bromide ligand) promotes the existence of an extensive network of weak C—H⋯X (X = F, Br) interactions. |
| format | Text |
| id | pubmed-3051521 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30515212011-04-26 (2,2′-Bipyridine-κ(2) N,N′)bromido(1,4,7-trithiacyclononane-κ(3) S,S′,S′′)ruthenium(II) hexafluoridophosphate Fernandes, José A. Almeida Paz, Filipe A. Ramos, Ana I. Santos, Teresa M. Braga, Susana S. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [RuBr(C(10)H(8)N(2))(C(6)H(12)S(3))]PF(6) or [RuBr(bpy)([9]aneS(3))]PF(6) ([9]aneS(3) is 1,4,7-trithiacyclononane and bpy is 2,2′-bipyridine), exhibits a very similar octahedral coordination geometry for the Ru(2+) atom to that of its [RuCl(bpy)([9]aneS(3))](+) analogue, with only the chloride ligand being substituted by a bromide ligand. The presence of a PF(6) (−) anion (alongside with the coordinated bromide ligand) promotes the existence of an extensive network of weak C—H⋯X (X = F, Br) interactions. International Union of Crystallography 2011-01-26 /pmc/articles/PMC3051521/ /pubmed/21522914 http://dx.doi.org/10.1107/S1600536811002662 Text en © Fernandes et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Fernandes, José A. Almeida Paz, Filipe A. Ramos, Ana I. Santos, Teresa M. Braga, Susana S. (2,2′-Bipyridine-κ(2) N,N′)bromido(1,4,7-trithiacyclononane-κ(3) S,S′,S′′)ruthenium(II) hexafluoridophosphate |
| title | (2,2′-Bipyridine-κ(2)
N,N′)bromido(1,4,7-trithiacyclononane-κ(3)
S,S′,S′′)ruthenium(II) hexafluoridophosphate |
| title_full | (2,2′-Bipyridine-κ(2)
N,N′)bromido(1,4,7-trithiacyclononane-κ(3)
S,S′,S′′)ruthenium(II) hexafluoridophosphate |
| title_fullStr | (2,2′-Bipyridine-κ(2)
N,N′)bromido(1,4,7-trithiacyclononane-κ(3)
S,S′,S′′)ruthenium(II) hexafluoridophosphate |
| title_full_unstemmed | (2,2′-Bipyridine-κ(2)
N,N′)bromido(1,4,7-trithiacyclononane-κ(3)
S,S′,S′′)ruthenium(II) hexafluoridophosphate |
| title_short | (2,2′-Bipyridine-κ(2)
N,N′)bromido(1,4,7-trithiacyclononane-κ(3)
S,S′,S′′)ruthenium(II) hexafluoridophosphate |
| title_sort | (2,2′-bipyridine-κ(2)
n,n′)bromido(1,4,7-trithiacyclononane-κ(3)
s,s′,s′′)ruthenium(ii) hexafluoridophosphate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051521/ https://www.ncbi.nlm.nih.gov/pubmed/21522914 http://dx.doi.org/10.1107/S1600536811002662 |
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