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Bis(2-amino-1,3-thia­zole-κN (3))diazido­zinc

In the title complex, [Zn(N(3))(2)(C(3)H(4)N(2)S)(2)], the Zn(II) atom is tetra­hedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-amino­thia­zole ligands. Intra­molecular N—H⋯N hydrogen bonds between the amino groups of both 2-amino­thia­zole ligands and t...

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Detalles Bibliográficos
Autores principales: Suh, Seung Wook, Kim, Chong-Hyeak, Kim, Inn Hoe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051526/
https://www.ncbi.nlm.nih.gov/pubmed/21522822
http://dx.doi.org/10.1107/S1600536810053766
Descripción
Sumario:In the title complex, [Zn(N(3))(2)(C(3)H(4)N(2)S)(2)], the Zn(II) atom is tetra­hedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-amino­thia­zole ligands. Intra­molecular N—H⋯N hydrogen bonds between the amino groups of both 2-amino­thia­zole ligands and the N atom of one of the azide ligands ensure that the heterocyclic rings are oriented in the same direction. Inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into zigzag sheets in the ac plane.