Bis(2-amino-1,3-thia­zole-κN (3))diazido­zinc

In the title complex, [Zn(N(3))(2)(C(3)H(4)N(2)S)(2)], the Zn(II) atom is tetra­hedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-amino­thia­zole ligands. Intra­molecular N—H⋯N hydrogen bonds between the amino groups of both 2-amino­thia­zole ligands and t...

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Detalles Bibliográficos
Autores principales: Suh, Seung Wook, Kim, Chong-Hyeak, Kim, Inn Hoe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051526/
https://www.ncbi.nlm.nih.gov/pubmed/21522822
http://dx.doi.org/10.1107/S1600536810053766
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author Suh, Seung Wook
Kim, Chong-Hyeak
Kim, Inn Hoe
author_facet Suh, Seung Wook
Kim, Chong-Hyeak
Kim, Inn Hoe
author_sort Suh, Seung Wook
collection PubMed
description In the title complex, [Zn(N(3))(2)(C(3)H(4)N(2)S)(2)], the Zn(II) atom is tetra­hedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-amino­thia­zole ligands. Intra­molecular N—H⋯N hydrogen bonds between the amino groups of both 2-amino­thia­zole ligands and the N atom of one of the azide ligands ensure that the heterocyclic rings are oriented in the same direction. Inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into zigzag sheets in the ac plane.
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spelling pubmed-30515262011-04-26 Bis(2-amino-1,3-thia­zole-κN (3))diazido­zinc Suh, Seung Wook Kim, Chong-Hyeak Kim, Inn Hoe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(N(3))(2)(C(3)H(4)N(2)S)(2)], the Zn(II) atom is tetra­hedrally coordinated by two terminal azide ligands and by the ring N atoms of two different 2-amino­thia­zole ligands. Intra­molecular N—H⋯N hydrogen bonds between the amino groups of both 2-amino­thia­zole ligands and the N atom of one of the azide ligands ensure that the heterocyclic rings are oriented in the same direction. Inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into zigzag sheets in the ac plane. International Union of Crystallography 2011-01-08 /pmc/articles/PMC3051526/ /pubmed/21522822 http://dx.doi.org/10.1107/S1600536810053766 Text en © Suh et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Suh, Seung Wook
Kim, Chong-Hyeak
Kim, Inn Hoe
Bis(2-amino-1,3-thia­zole-κN (3))diazido­zinc
title Bis(2-amino-1,3-thia­zole-κN (3))diazido­zinc
title_full Bis(2-amino-1,3-thia­zole-κN (3))diazido­zinc
title_fullStr Bis(2-amino-1,3-thia­zole-κN (3))diazido­zinc
title_full_unstemmed Bis(2-amino-1,3-thia­zole-κN (3))diazido­zinc
title_short Bis(2-amino-1,3-thia­zole-κN (3))diazido­zinc
title_sort bis(2-amino-1,3-thia­zole-κn (3))diazido­zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051526/
https://www.ncbi.nlm.nih.gov/pubmed/21522822
http://dx.doi.org/10.1107/S1600536810053766
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