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[μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As’]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthenium(0)

In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)], the bis­(diphenyl­arsanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom. Both arsine and phosphane ligands are equatorial with respect to the Ru(3) tria...

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Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Hafiz Malik, H. A., Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051533/
https://www.ncbi.nlm.nih.gov/pubmed/21522853
http://dx.doi.org/10.1107/S1600536810054206
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author Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Hafiz Malik, H. A.
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Hafiz Malik, H. A.
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Shawkataly, Omar bin
collection PubMed
description In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)], the bis­(diphenyl­arsanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom. Both arsine and phosphane ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphane-substituted benzene rings make dihedral angles of 57.91 (19), 84.31 (15) and 59.37 (18)° with each other. The dihedral angles between the two benzene rings are 60.9 (2) and 85.40 (18)° for the two diphenyl­arsanyl groups. In the crystal, mol­ecules are linked into a three-dimensional framework by inter­molecular C—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯π inter­actions stabilize the crystal structure.
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spelling pubmed-30515332011-04-26 [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As’]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)], the bis­(diphenyl­arsanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom. Both arsine and phosphane ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphane-substituted benzene rings make dihedral angles of 57.91 (19), 84.31 (15) and 59.37 (18)° with each other. The dihedral angles between the two benzene rings are 60.9 (2) and 85.40 (18)° for the two diphenyl­arsanyl groups. In the crystal, mol­ecules are linked into a three-dimensional framework by inter­molecular C—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯π inter­actions stabilize the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051533/ /pubmed/21522853 http://dx.doi.org/10.1107/S1600536810054206 Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Hafiz Malik, H. A.
Yeap, Chin Sing
Fun, Hoong-Kun
[μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As’]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthenium(0)
title [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As’]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthenium(0)
title_full [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As’]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthenium(0)
title_fullStr [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As’]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthenium(0)
title_full_unstemmed [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As’]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthenium(0)
title_short [μ-Bis(diphenyl­arsanyl)methane-1:2κ(2) As:As’]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κP]-triangulo-triruthenium(0)
title_sort [μ-bis(diphenyl­arsanyl)methane-1:2κ(2) as:as’]nona­carbonyl-1κ(3) c,2κ(3) c,3κ(3) c-[(4-methyl­sulfanylphen­yl)diphenyl­phosphane-3κp]-triangulo-triruthenium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051533/
https://www.ncbi.nlm.nih.gov/pubmed/21522853
http://dx.doi.org/10.1107/S1600536810054206
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