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[μ-Bis(diphenylarsanyl)methane-1:2κ(2) As:As’]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)], the bis(diphenylarsanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom. Both arsine and phosphane ligands are equatorial with respect to the Ru(3) tria...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051533/ https://www.ncbi.nlm.nih.gov/pubmed/21522853 http://dx.doi.org/10.1107/S1600536810054206 |
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author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Shawkataly, Omar bin |
collection | PubMed |
description | In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)], the bis(diphenylarsanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom. Both arsine and phosphane ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphane-substituted benzene rings make dihedral angles of 57.91 (19), 84.31 (15) and 59.37 (18)° with each other. The dihedral angles between the two benzene rings are 60.9 (2) and 85.40 (18)° for the two diphenylarsanyl groups. In the crystal, molecules are linked into a three-dimensional framework by intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions stabilize the crystal structure. |
format | Text |
id | pubmed-3051533 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30515332011-04-26 [μ-Bis(diphenylarsanyl)methane-1:2κ(2) As:As’]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title triangulo-triruthenium compound, [Ru(3)(C(25)H(22)As(2))(C(19)H(17)PS)(CO)(9)], the bis(diphenylarsanyl)methane ligand bridges an Ru—Ru bond and the monodentate phosphane ligand bonds to the third Ru atom. Both arsine and phosphane ligands are equatorial with respect to the Ru(3) triangle. In addition, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three phosphane-substituted benzene rings make dihedral angles of 57.91 (19), 84.31 (15) and 59.37 (18)° with each other. The dihedral angles between the two benzene rings are 60.9 (2) and 85.40 (18)° for the two diphenylarsanyl groups. In the crystal, molecules are linked into a three-dimensional framework by intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions stabilize the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051533/ /pubmed/21522853 http://dx.doi.org/10.1107/S1600536810054206 Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Hafiz Malik, H. A. Yeap, Chin Sing Fun, Hoong-Kun [μ-Bis(diphenylarsanyl)methane-1:2κ(2) As:As’]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0) |
title | [μ-Bis(diphenylarsanyl)methane-1:2κ(2)
As:As’]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0) |
title_full | [μ-Bis(diphenylarsanyl)methane-1:2κ(2)
As:As’]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0) |
title_fullStr | [μ-Bis(diphenylarsanyl)methane-1:2κ(2)
As:As’]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0) |
title_full_unstemmed | [μ-Bis(diphenylarsanyl)methane-1:2κ(2)
As:As’]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0) |
title_short | [μ-Bis(diphenylarsanyl)methane-1:2κ(2)
As:As’]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-[(4-methylsulfanylphenyl)diphenylphosphane-3κP]-triangulo-triruthenium(0) |
title_sort | [μ-bis(diphenylarsanyl)methane-1:2κ(2)
as:as’]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-[(4-methylsulfanylphenyl)diphenylphosphane-3κp]-triangulo-triruthenium(0) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051533/ https://www.ncbi.nlm.nih.gov/pubmed/21522853 http://dx.doi.org/10.1107/S1600536810054206 |
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