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Cinnarizinium dipicrate
In the cinnarizinium dication of the title compound {systematic name: 1-diphenylmethyl-4-[(2E)-3-phenylprop-2-en-1-yl]piperazine-1,4-diium bis(2,4,6-trinitrophenolate)}, C(26)H(30)N(2) (2+)·2C(6)H(2)N(3)O(7) (−), the piperazine group is protonated at both N atoms and adopts a slightly distorted...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051536/ https://www.ncbi.nlm.nih.gov/pubmed/21523154 http://dx.doi.org/10.1107/S1600536811002674 |
Sumario: | In the cinnarizinium dication of the title compound {systematic name: 1-diphenylmethyl-4-[(2E)-3-phenylprop-2-en-1-yl]piperazine-1,4-diium bis(2,4,6-trinitrophenolate)}, C(26)H(30)N(2) (2+)·2C(6)H(2)N(3)O(7) (−), the piperazine group is protonated at both N atoms and adopts a slightly distorted chair conformation. Strong N—H⋯O(hydroxy) cation–anion hydrogen bonds link the dication and two anions. In the cation, the (2E)-3-phenylprop-2-en-1-yl fragment is disordered over two positions in a ratio of 0.586 (4): 0.414 (4). Two nitro groups in one anion and three in the other one demonstrate rotational disorder. The crystal packing is stabilized by weak intermolecular π–π [centroid–centroid distances = 3.844 (7), 3.677 (9), 3.825 (5), 3.634 (2) and 3.729 (7) Å], C—H⋯π and C—H⋯O interactions. |
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