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Cinnarizinium dipicrate

In the cinnarizinium dication of the title compound {systematic name: 1-diphenyl­methyl-4-[(2E)-3-phenyl­prop-2-en-1-yl]piperazine-1,4-diium bis­(2,4,6-trinitro­phenolate)}, C(26)H(30)N(2) (2+)·2C(6)H(2)N(3)O(7) (−), the piperazine group is protonated at both N atoms and adopts a slightly distorted...

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Detalles Bibliográficos
Autores principales: Jasinski, Jerry P., Butcher, Ray J., Siddegowda, M. S., Yathirajan, H. S., Chidan Kumar, C. S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051536/
https://www.ncbi.nlm.nih.gov/pubmed/21523154
http://dx.doi.org/10.1107/S1600536811002674
Descripción
Sumario:In the cinnarizinium dication of the title compound {systematic name: 1-diphenyl­methyl-4-[(2E)-3-phenyl­prop-2-en-1-yl]piperazine-1,4-diium bis­(2,4,6-trinitro­phenolate)}, C(26)H(30)N(2) (2+)·2C(6)H(2)N(3)O(7) (−), the piperazine group is protonated at both N atoms and adopts a slightly distorted chair conformation. Strong N—H⋯O(hy­droxy) cation–anion hydrogen bonds link the dication and two anions. In the cation, the (2E)-3-phenyl­prop-2-en-1-yl fragment is disordered over two positions in a ratio of 0.586 (4): 0.414 (4). Two nitro groups in one anion and three in the other one demonstrate rotational disorder. The crystal packing is stabilized by weak inter­molecular π–π [centroid–centroid distances = 3.844 (7), 3.677 (9), 3.825 (5), 3.634 (2) and 3.729 (7) Å], C—H⋯π and C—H⋯O inter­actions.