Chloridonitros­yl[meso-5,10,15,20-tetra­kis­(p-tol­yl)porphyrinato-κ(4) N,N′,N′′,N′′′]osmium(II) tetra­hydro­furan tetra­solvate

The title compound, [OsCl(NO)(C(48)H(36)N(4))]·4C(4)H(8)O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octa­hedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. T...

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Detalles Bibliográficos
Autores principales: Chen, Li, Xu, Nan, Powell, Douglas R., Richter-Addo, George B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051540/
https://www.ncbi.nlm.nih.gov/pubmed/21522883
http://dx.doi.org/10.1107/S1600536811001401
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author Chen, Li
Xu, Nan
Powell, Douglas R.
Richter-Addo, George B.
author_facet Chen, Li
Xu, Nan
Powell, Douglas R.
Richter-Addo, George B.
author_sort Chen, Li
collection PubMed
description The title compound, [OsCl(NO)(C(48)H(36)N(4))]·4C(4)H(8)O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octa­hedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio.
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spelling pubmed-30515402011-04-26 Chloridonitros­yl[meso-5,10,15,20-tetra­kis­(p-tol­yl)porphyrinato-κ(4) N,N′,N′′,N′′′]osmium(II) tetra­hydro­furan tetra­solvate Chen, Li Xu, Nan Powell, Douglas R. Richter-Addo, George B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [OsCl(NO)(C(48)H(36)N(4))]·4C(4)H(8)O, is a six-coordinate osmium(II) porphyrin complex with nitrosyl (NO) and chloride (Cl) ligands trans to each other in an octa­hedral geometry. The metal complex lies on a fourfold rotation axis that passes through the Os, N, O and Cl atoms. The NO and Cl ligands are disordered in an 0.511 (12):0.486 (12) ratio. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051540/ /pubmed/21522883 http://dx.doi.org/10.1107/S1600536811001401 Text en © Chen et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Li
Xu, Nan
Powell, Douglas R.
Richter-Addo, George B.
Chloridonitros­yl[meso-5,10,15,20-tetra­kis­(p-tol­yl)porphyrinato-κ(4) N,N′,N′′,N′′′]osmium(II) tetra­hydro­furan tetra­solvate
title Chloridonitros­yl[meso-5,10,15,20-tetra­kis­(p-tol­yl)porphyrinato-κ(4) N,N′,N′′,N′′′]osmium(II) tetra­hydro­furan tetra­solvate
title_full Chloridonitros­yl[meso-5,10,15,20-tetra­kis­(p-tol­yl)porphyrinato-κ(4) N,N′,N′′,N′′′]osmium(II) tetra­hydro­furan tetra­solvate
title_fullStr Chloridonitros­yl[meso-5,10,15,20-tetra­kis­(p-tol­yl)porphyrinato-κ(4) N,N′,N′′,N′′′]osmium(II) tetra­hydro­furan tetra­solvate
title_full_unstemmed Chloridonitros­yl[meso-5,10,15,20-tetra­kis­(p-tol­yl)porphyrinato-κ(4) N,N′,N′′,N′′′]osmium(II) tetra­hydro­furan tetra­solvate
title_short Chloridonitros­yl[meso-5,10,15,20-tetra­kis­(p-tol­yl)porphyrinato-κ(4) N,N′,N′′,N′′′]osmium(II) tetra­hydro­furan tetra­solvate
title_sort chloridonitros­yl[meso-5,10,15,20-tetra­kis­(p-tol­yl)porphyrinato-κ(4) n,n′,n′′,n′′′]osmium(ii) tetra­hydro­furan tetra­solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051540/
https://www.ncbi.nlm.nih.gov/pubmed/21522883
http://dx.doi.org/10.1107/S1600536811001401
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AT xunan chloridonitrosylmeso5101520tetrakisptolylporphyrinatok4nnnnosmiumiitetrahydrofurantetrasolvate
AT powelldouglasr chloridonitrosylmeso5101520tetrakisptolylporphyrinatok4nnnnosmiumiitetrahydrofurantetrasolvate
AT richteraddogeorgeb chloridonitrosylmeso5101520tetrakisptolylporphyrinatok4nnnnosmiumiitetrahydrofurantetrasolvate

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