Methyl­(phenyl)­bis­(quinoline-2-carbox­ylato-κ(2) N,O)tin(IV) monohydrate

The Sn(IV) atom in each of the two independent mol­ecules in the asymmetric unit of the title compound, [Sn(CH(3))(C(6)H(5))(C(10)H(6)NO(2))(2)]·H(2)O, is N,O-chelated by two quinoline-2-carboxyl­ate ions; the dative Sn—N bonds are significantly longer than the covalent Sn—O bonds. The two O and two...

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Detalles Bibliográficos
Autores principales: Vafaee, Marzieh, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051546/
https://www.ncbi.nlm.nih.gov/pubmed/21522838
http://dx.doi.org/10.1107/S1600536810054437
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author Vafaee, Marzieh
Amini, Mostafa M.
Ng, Seik Weng
author_facet Vafaee, Marzieh
Amini, Mostafa M.
Ng, Seik Weng
author_sort Vafaee, Marzieh
collection PubMed
description The Sn(IV) atom in each of the two independent mol­ecules in the asymmetric unit of the title compound, [Sn(CH(3))(C(6)H(5))(C(10)H(6)NO(2))(2)]·H(2)O, is N,O-chelated by two quinoline-2-carboxyl­ate ions; the dative Sn—N bonds are significantly longer than the covalent Sn—O bonds. The two O and two N atoms comprise a trapezoid, and the diorganotin skeleton is bent over the longer N—N edge [C—Sn—C = 144.2 (1) and 144.5 (1)° in the two independent mol­ecules]. The uncoordinated water mol­ecules serve to connect the skew-trapezoidal bipyramidal tin-bearing mol­ecules, generating a linear chain motif running along the ac diagonal. The crystal studied was a non-merohedral twin having a minor component of 33.2 (1)%.
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spelling pubmed-30515462011-04-26 Methyl­(phenyl)­bis­(quinoline-2-carbox­ylato-κ(2) N,O)tin(IV) monohydrate Vafaee, Marzieh Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in each of the two independent mol­ecules in the asymmetric unit of the title compound, [Sn(CH(3))(C(6)H(5))(C(10)H(6)NO(2))(2)]·H(2)O, is N,O-chelated by two quinoline-2-carboxyl­ate ions; the dative Sn—N bonds are significantly longer than the covalent Sn—O bonds. The two O and two N atoms comprise a trapezoid, and the diorganotin skeleton is bent over the longer N—N edge [C—Sn—C = 144.2 (1) and 144.5 (1)° in the two independent mol­ecules]. The uncoordinated water mol­ecules serve to connect the skew-trapezoidal bipyramidal tin-bearing mol­ecules, generating a linear chain motif running along the ac diagonal. The crystal studied was a non-merohedral twin having a minor component of 33.2 (1)%. International Union of Crystallography 2011-01-12 /pmc/articles/PMC3051546/ /pubmed/21522838 http://dx.doi.org/10.1107/S1600536810054437 Text en © Vafaee et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vafaee, Marzieh
Amini, Mostafa M.
Ng, Seik Weng
Methyl­(phenyl)­bis­(quinoline-2-carbox­ylato-κ(2) N,O)tin(IV) monohydrate
title Methyl­(phenyl)­bis­(quinoline-2-carbox­ylato-κ(2) N,O)tin(IV) monohydrate
title_full Methyl­(phenyl)­bis­(quinoline-2-carbox­ylato-κ(2) N,O)tin(IV) monohydrate
title_fullStr Methyl­(phenyl)­bis­(quinoline-2-carbox­ylato-κ(2) N,O)tin(IV) monohydrate
title_full_unstemmed Methyl­(phenyl)­bis­(quinoline-2-carbox­ylato-κ(2) N,O)tin(IV) monohydrate
title_short Methyl­(phenyl)­bis­(quinoline-2-carbox­ylato-κ(2) N,O)tin(IV) monohydrate
title_sort methyl­(phenyl)­bis­(quinoline-2-carbox­ylato-κ(2) n,o)tin(iv) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051546/
https://www.ncbi.nlm.nih.gov/pubmed/21522838
http://dx.doi.org/10.1107/S1600536810054437
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AT aminimostafam methylphenylbisquinoline2carboxylatok2notinivmonohydrate
AT ngseikweng methylphenylbisquinoline2carboxylatok2notinivmonohydrate

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