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Bis(μ(2)-quinoline-2-carboxyl­ato)-κ(3) N,O (1):O (1);κ(3) O (1):N,O (1)-bis­[(acetato-κO)(ethanol-κO)lead(II)]

In the centrosymmetric dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(C(2)H(5)OH)(2)], one O atom of the carboxyl­ate group of the quinoline-2-carboxyl­ate anion connects the two Pb(II) atoms. The Pb(II) atom is surrounded by four O atoms and one N atom in a Ψ-octa­hedral PbO(4)NE...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051551/
https://www.ncbi.nlm.nih.gov/pubmed/21522915
http://dx.doi.org/10.1107/S1600536811002509
Descripción
Sumario:In the centrosymmetric dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(C(2)H(5)OH)(2)], one O atom of the carboxyl­ate group of the quinoline-2-carboxyl­ate anion connects the two Pb(II) atoms. The Pb(II) atom is surrounded by four O atoms and one N atom in a Ψ-octa­hedral PbO(4)NE geometry (E is the electron lone pair). Two longer Pb⋯O inter­actions distort the geometry towards a Ψ-square-anti­prism. Inter­molecular O—H⋯O hydrogen bonds link the mol­ecules.