Bis(μ(2)-quinoline-2-carboxyl­ato)-κ(3) N,O (1):O (1);κ(3) O (1):N,O (1)-bis­[(acetato-κO)(ethanol-κO)lead(II)]

In the centrosymmetric dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(C(2)H(5)OH)(2)], one O atom of the carboxyl­ate group of the quinoline-2-carboxyl­ate anion connects the two Pb(II) atoms. The Pb(II) atom is surrounded by four O atoms and one N atom in a Ψ-octa­hedral PbO(4)NE...

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Detalles Bibliográficos
Autores principales: Najafi, Ezzatollah, Amini, Mostafa M., Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051551/
https://www.ncbi.nlm.nih.gov/pubmed/21522915
http://dx.doi.org/10.1107/S1600536811002509
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author Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_facet Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
author_sort Najafi, Ezzatollah
collection PubMed
description In the centrosymmetric dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(C(2)H(5)OH)(2)], one O atom of the carboxyl­ate group of the quinoline-2-carboxyl­ate anion connects the two Pb(II) atoms. The Pb(II) atom is surrounded by four O atoms and one N atom in a Ψ-octa­hedral PbO(4)NE geometry (E is the electron lone pair). Two longer Pb⋯O inter­actions distort the geometry towards a Ψ-square-anti­prism. Inter­molecular O—H⋯O hydrogen bonds link the mol­ecules.
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spelling pubmed-30515512011-04-26 Bis(μ(2)-quinoline-2-carboxyl­ato)-κ(3) N,O (1):O (1);κ(3) O (1):N,O (1)-bis­[(acetato-κO)(ethanol-κO)lead(II)] Najafi, Ezzatollah Amini, Mostafa M. Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(C(2)H(5)OH)(2)], one O atom of the carboxyl­ate group of the quinoline-2-carboxyl­ate anion connects the two Pb(II) atoms. The Pb(II) atom is surrounded by four O atoms and one N atom in a Ψ-octa­hedral PbO(4)NE geometry (E is the electron lone pair). Two longer Pb⋯O inter­actions distort the geometry towards a Ψ-square-anti­prism. Inter­molecular O—H⋯O hydrogen bonds link the mol­ecules. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051551/ /pubmed/21522915 http://dx.doi.org/10.1107/S1600536811002509 Text en © Najafi et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Najafi, Ezzatollah
Amini, Mostafa M.
Ng, Seik Weng
Bis(μ(2)-quinoline-2-carboxyl­ato)-κ(3) N,O (1):O (1);κ(3) O (1):N,O (1)-bis­[(acetato-κO)(ethanol-κO)lead(II)]
title Bis(μ(2)-quinoline-2-carboxyl­ato)-κ(3) N,O (1):O (1);κ(3) O (1):N,O (1)-bis­[(acetato-κO)(ethanol-κO)lead(II)]
title_full Bis(μ(2)-quinoline-2-carboxyl­ato)-κ(3) N,O (1):O (1);κ(3) O (1):N,O (1)-bis­[(acetato-κO)(ethanol-κO)lead(II)]
title_fullStr Bis(μ(2)-quinoline-2-carboxyl­ato)-κ(3) N,O (1):O (1);κ(3) O (1):N,O (1)-bis­[(acetato-κO)(ethanol-κO)lead(II)]
title_full_unstemmed Bis(μ(2)-quinoline-2-carboxyl­ato)-κ(3) N,O (1):O (1);κ(3) O (1):N,O (1)-bis­[(acetato-κO)(ethanol-κO)lead(II)]
title_short Bis(μ(2)-quinoline-2-carboxyl­ato)-κ(3) N,O (1):O (1);κ(3) O (1):N,O (1)-bis­[(acetato-κO)(ethanol-κO)lead(II)]
title_sort bis(μ(2)-quinoline-2-carboxyl­ato)-κ(3) n,o (1):o (1);κ(3) o (1):n,o (1)-bis­[(acetato-κo)(ethanol-κo)lead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051551/
https://www.ncbi.nlm.nih.gov/pubmed/21522915
http://dx.doi.org/10.1107/S1600536811002509
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