rac-(rel-1R,2R,4S)-Spiro­[bicyclo­[2.2.1]heptane-2,3′-indol]-2′-amine

In the racemic title compound, C(14)H(16)N(2), the aromatic ring component of the amino­indoline system occupies the endo cavity of the norbornane component. The aromatic ring lies at an angle of 74.12 (5)° to the plane defined by the four C atoms that comprises the rigid part of the boat-shaped six...

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Detalles Bibliográficos
Autores principales: Lemmerer, Andreas, Michael, Joseph P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051556/
https://www.ncbi.nlm.nih.gov/pubmed/21523067
http://dx.doi.org/10.1107/S1600536811001048
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author Lemmerer, Andreas
Michael, Joseph P.
author_facet Lemmerer, Andreas
Michael, Joseph P.
author_sort Lemmerer, Andreas
collection PubMed
description In the racemic title compound, C(14)H(16)N(2), the aromatic ring component of the amino­indoline system occupies the endo cavity of the norbornane component. The aromatic ring lies at an angle of 74.12 (5)° to the plane defined by the four C atoms that comprises the rigid part of the boat-shaped six-membered ring of the norbornane unit. Pairs of mol­ecules assemble in the crystal structure, forming centrosymmetric hydrogen-bonded dimers via pairs of N—H⋯N hydrogen bonds through the syn H atom of the amine group.
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spelling pubmed-30515562011-04-26 rac-(rel-1R,2R,4S)-Spiro­[bicyclo­[2.2.1]heptane-2,3′-indol]-2′-amine Lemmerer, Andreas Michael, Joseph P. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the racemic title compound, C(14)H(16)N(2), the aromatic ring component of the amino­indoline system occupies the endo cavity of the norbornane component. The aromatic ring lies at an angle of 74.12 (5)° to the plane defined by the four C atoms that comprises the rigid part of the boat-shaped six-membered ring of the norbornane unit. Pairs of mol­ecules assemble in the crystal structure, forming centrosymmetric hydrogen-bonded dimers via pairs of N—H⋯N hydrogen bonds through the syn H atom of the amine group. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051556/ /pubmed/21523067 http://dx.doi.org/10.1107/S1600536811001048 Text en © Lemmerer and Michael 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lemmerer, Andreas
Michael, Joseph P.
rac-(rel-1R,2R,4S)-Spiro­[bicyclo­[2.2.1]heptane-2,3′-indol]-2′-amine
title rac-(rel-1R,2R,4S)-Spiro­[bicyclo­[2.2.1]heptane-2,3′-indol]-2′-amine
title_full rac-(rel-1R,2R,4S)-Spiro­[bicyclo­[2.2.1]heptane-2,3′-indol]-2′-amine
title_fullStr rac-(rel-1R,2R,4S)-Spiro­[bicyclo­[2.2.1]heptane-2,3′-indol]-2′-amine
title_full_unstemmed rac-(rel-1R,2R,4S)-Spiro­[bicyclo­[2.2.1]heptane-2,3′-indol]-2′-amine
title_short rac-(rel-1R,2R,4S)-Spiro­[bicyclo­[2.2.1]heptane-2,3′-indol]-2′-amine
title_sort rac-(rel-1r,2r,4s)-spiro­[bicyclo­[2.2.1]heptane-2,3′-indol]-2′-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051556/
https://www.ncbi.nlm.nih.gov/pubmed/21523067
http://dx.doi.org/10.1107/S1600536811001048
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