Tris(ethane-1,2-diamine-κ(2) N,N′)nickel(II) 5-hy­droxy­isophthalate monohydrate

The asymmetric unit of the title compound, [Ni(C(2)H(8)N(2))(3)](C(8)H(4)O(5))·H(2)O, contains one [Ni(en)(3)](2+) cation (en is ethane-1,2-diamine), one 5-hy­droxy­isophthalate dianion and one water mol­ecule. In the cation, the Ni(2+) ion is coordinated by six N atoms from three ethyl­enediamine l...

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Detalles Bibliográficos
Autores principales: Wang, Shu-Hong, Zhang, Bin, Wang, Cheng, Xu, Guo-Qiang, Xie, Yang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051561/
https://www.ncbi.nlm.nih.gov/pubmed/21522910
http://dx.doi.org/10.1107/S1600536811001449
Descripción
Sumario:The asymmetric unit of the title compound, [Ni(C(2)H(8)N(2))(3)](C(8)H(4)O(5))·H(2)O, contains one [Ni(en)(3)](2+) cation (en is ethane-1,2-diamine), one 5-hy­droxy­isophthalate dianion and one water mol­ecule. In the cation, the Ni(2+) ion is coordinated by six N atoms from three ethyl­enediamine ligands in a distorted octa­hedral geometry. The complex ions and water mol­ecules are linked by weak N—H⋯N/O and O—H⋯N/O hydrogen bonds into a three-demensional structure.

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