3-Hy­droxy-2-[(4-hy­droxy-3,5-dimeth­oxy­phen­yl)(2-hy­droxy-4,4-dimethyl-6-oxo­cyclo­hex-1-en-1-yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one

In the title compound, C(25)H(32)O(7), the 3-hy­droxy-5,5-dimethyl­cyclo­hex-2-enone rings adopt slightly distorted envelope conformations with the two planes at the base of the envelope forming dihedral angles of 57.6 (4) and 53.9 (9)° with the benzene ring. There is an intra­molecular hy­droxy–ket...

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Detalles Bibliográficos
Autores principales: Yang, Xiao-Hui, Zhou, Yong-Hong, Zhang, Meng, Hu, Li-Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051563/
https://www.ncbi.nlm.nih.gov/pubmed/21523148
http://dx.doi.org/10.1107/S1600536811002698
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author Yang, Xiao-Hui
Zhou, Yong-Hong
Zhang, Meng
Hu, Li-Hong
author_facet Yang, Xiao-Hui
Zhou, Yong-Hong
Zhang, Meng
Hu, Li-Hong
author_sort Yang, Xiao-Hui
collection PubMed
description In the title compound, C(25)H(32)O(7), the 3-hy­droxy-5,5-dimethyl­cyclo­hex-2-enone rings adopt slightly distorted envelope conformations with the two planes at the base of the envelope forming dihedral angles of 57.6 (4) and 53.9 (9)° with the benzene ring. There is an intra­molecular hy­droxy–ketone O—H⋯O inter­action between the two substituted cyclo­hexane rings as well as a short intra­molecular phenol–meth­oxy O—H⋯O inter­action.
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spelling pubmed-30515632011-04-26 3-Hy­droxy-2-[(4-hy­droxy-3,5-dimeth­oxy­phen­yl)(2-hy­droxy-4,4-dimethyl-6-oxo­cyclo­hex-1-en-1-yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one Yang, Xiao-Hui Zhou, Yong-Hong Zhang, Meng Hu, Li-Hong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(32)O(7), the 3-hy­droxy-5,5-dimethyl­cyclo­hex-2-enone rings adopt slightly distorted envelope conformations with the two planes at the base of the envelope forming dihedral angles of 57.6 (4) and 53.9 (9)° with the benzene ring. There is an intra­molecular hy­droxy–ketone O—H⋯O inter­action between the two substituted cyclo­hexane rings as well as a short intra­molecular phenol–meth­oxy O—H⋯O inter­action. International Union of Crystallography 2011-01-26 /pmc/articles/PMC3051563/ /pubmed/21523148 http://dx.doi.org/10.1107/S1600536811002698 Text en © Yang et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yang, Xiao-Hui
Zhou, Yong-Hong
Zhang, Meng
Hu, Li-Hong
3-Hy­droxy-2-[(4-hy­droxy-3,5-dimeth­oxy­phen­yl)(2-hy­droxy-4,4-dimethyl-6-oxo­cyclo­hex-1-en-1-yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title 3-Hy­droxy-2-[(4-hy­droxy-3,5-dimeth­oxy­phen­yl)(2-hy­droxy-4,4-dimethyl-6-oxo­cyclo­hex-1-en-1-yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title_full 3-Hy­droxy-2-[(4-hy­droxy-3,5-dimeth­oxy­phen­yl)(2-hy­droxy-4,4-dimethyl-6-oxo­cyclo­hex-1-en-1-yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title_fullStr 3-Hy­droxy-2-[(4-hy­droxy-3,5-dimeth­oxy­phen­yl)(2-hy­droxy-4,4-dimethyl-6-oxo­cyclo­hex-1-en-1-yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title_full_unstemmed 3-Hy­droxy-2-[(4-hy­droxy-3,5-dimeth­oxy­phen­yl)(2-hy­droxy-4,4-dimethyl-6-oxo­cyclo­hex-1-en-1-yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title_short 3-Hy­droxy-2-[(4-hy­droxy-3,5-dimeth­oxy­phen­yl)(2-hy­droxy-4,4-dimethyl-6-oxo­cyclo­hex-1-en-1-yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
title_sort 3-hy­droxy-2-[(4-hy­droxy-3,5-dimeth­oxy­phen­yl)(2-hy­droxy-4,4-dimethyl-6-oxo­cyclo­hex-1-en-1-yl)meth­yl]-5,5-dimethyl­cyclo­hex-2-en-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051563/
https://www.ncbi.nlm.nih.gov/pubmed/21523148
http://dx.doi.org/10.1107/S1600536811002698
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AT zhangmeng 3hydroxy24hydroxy35dimethoxyphenyl2hydroxy44dimethyl6oxocyclohex1en1ylmethyl55dimethylcyclohex2en1one
AT hulihong 3hydroxy24hydroxy35dimethoxyphenyl2hydroxy44dimethyl6oxocyclohex1en1ylmethyl55dimethylcyclohex2en1one

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