2-Meth­oxy­ethanaminium periodate 18-crown-6 clathrate

In the crystal structure of the title organic salt, C(3)H(10)NO(+)·IO(4) (−)·C(12)H(24)O(6), the protonated 2-meth­oxy­ethanaminium (CH(3)OC(2)H(4)—NH(3) (+)) cation forms a 1:1 supra­molecular rotator–stator complex with the 18-crown-6 mol­ecule via N—H⋯O hydrogen bonds. The (CH(3)OC(2)H(4)—NH(3) (...

Descripción completa

Detalles Bibliográficos
Autor principal: Hu, Jin-Gang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051565/
https://www.ncbi.nlm.nih.gov/pubmed/21523131
http://dx.doi.org/10.1107/S1600536811002315
_version_ 1782199509258862592
author Hu, Jin-Gang
author_facet Hu, Jin-Gang
author_sort Hu, Jin-Gang
collection PubMed
description In the crystal structure of the title organic salt, C(3)H(10)NO(+)·IO(4) (−)·C(12)H(24)O(6), the protonated 2-meth­oxy­ethanaminium (CH(3)OC(2)H(4)—NH(3) (+)) cation forms a 1:1 supra­molecular rotator–stator complex with the 18-crown-6 mol­ecule via N—H⋯O hydrogen bonds. The (CH(3)OC(2)H(4)—NH(3) (+)) group is attached from the convex side of the bowl-shaped crown, in contrast to similar ammonium cations that nest in the curvature of the bowl. The cations are associated via N—H⋯O inter­actions, while the cations and anions are linked by weak C—H⋯O hydrogen bonds, forming cation–crown–anion chains parallel to [010].
format Text
id pubmed-3051565
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30515652011-04-26 2-Meth­oxy­ethanaminium periodate 18-crown-6 clathrate Hu, Jin-Gang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title organic salt, C(3)H(10)NO(+)·IO(4) (−)·C(12)H(24)O(6), the protonated 2-meth­oxy­ethanaminium (CH(3)OC(2)H(4)—NH(3) (+)) cation forms a 1:1 supra­molecular rotator–stator complex with the 18-crown-6 mol­ecule via N—H⋯O hydrogen bonds. The (CH(3)OC(2)H(4)—NH(3) (+)) group is attached from the convex side of the bowl-shaped crown, in contrast to similar ammonium cations that nest in the curvature of the bowl. The cations are associated via N—H⋯O inter­actions, while the cations and anions are linked by weak C—H⋯O hydrogen bonds, forming cation–crown–anion chains parallel to [010]. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051565/ /pubmed/21523131 http://dx.doi.org/10.1107/S1600536811002315 Text en © Jin-Gang Hu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hu, Jin-Gang
2-Meth­oxy­ethanaminium periodate 18-crown-6 clathrate
title 2-Meth­oxy­ethanaminium periodate 18-crown-6 clathrate
title_full 2-Meth­oxy­ethanaminium periodate 18-crown-6 clathrate
title_fullStr 2-Meth­oxy­ethanaminium periodate 18-crown-6 clathrate
title_full_unstemmed 2-Meth­oxy­ethanaminium periodate 18-crown-6 clathrate
title_short 2-Meth­oxy­ethanaminium periodate 18-crown-6 clathrate
title_sort 2-meth­oxy­ethanaminium periodate 18-crown-6 clathrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051565/
https://www.ncbi.nlm.nih.gov/pubmed/21523131
http://dx.doi.org/10.1107/S1600536811002315
work_keys_str_mv AT hujingang 2methoxyethanaminiumperiodate18crown6clathrate

Ejemplares similares