Diaqua­(6-bromo­picolinato-κ(2) N,O)(nitrato-κ(2) O,O)copper(II)

In the monomeric title complex, [Cu(C(6)H(3)BrNO(2))(NO(3))(H(2)O)(2)], the Cu(II) ion is coordinated by a bidentate 6-bromo­picolinate ion, one nitrate ion and two water mol­ecules in a geometry inter­mediate between five- and six-coordinate. Conventional O—H⋯O hydrogen bonds link the complex mol­e...

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Detalles Bibliográficos
Autores principales: Silva, Joana A., Pereira Magalhães, Ana, Ramos Silva, Manuela, Sobral, Abílio J. F. N., Pereira, Laura C. J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051566/
https://www.ncbi.nlm.nih.gov/pubmed/21522841
http://dx.doi.org/10.1107/S160053681100064X
Descripción
Sumario:In the monomeric title complex, [Cu(C(6)H(3)BrNO(2))(NO(3))(H(2)O)(2)], the Cu(II) ion is coordinated by a bidentate 6-bromo­picolinate ion, one nitrate ion and two water mol­ecules in a geometry inter­mediate between five- and six-coordinate. Conventional O—H⋯O hydrogen bonds link the complex mol­ecules, forming layers parallel to the ab plane.

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