Cargando…

catena-Poly[[[aqua­chlorido­manganese(II)]-bis­[μ-1,1′-(oxydi-p-phenyl­ene)di-1H-imidazole-κ(2) N (3):N (3′)]] chloride dimethyl­formamide mono­solvate monohydrate]

The title coordination polymer, {[MnCl(C(18)H(14)N(4)O)(2)(H(2)O)]Cl·C(3)H(7)NO·H(2)O}(n), obtained by the solvothermal reaction of BIDPE and manganese(II) salt in H(2)O/DMF (DMF is dimethyl­formamide), is composed of a chain of [Mn(2)(BIDPE)(2)] [BIDPE is 1,1′-(oxydi-p-phenyl­ene)di-1H-imidazole] m...

Descripción completa

Detalles Bibliográficos
Autor principal: Mu, Xiao-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051568/
https://www.ncbi.nlm.nih.gov/pubmed/21522845
http://dx.doi.org/10.1107/S1600536810054383
_version_ 1782199509942534144
author Mu, Xiao-Long
author_facet Mu, Xiao-Long
author_sort Mu, Xiao-Long
collection PubMed
description The title coordination polymer, {[MnCl(C(18)H(14)N(4)O)(2)(H(2)O)]Cl·C(3)H(7)NO·H(2)O}(n), obtained by the solvothermal reaction of BIDPE and manganese(II) salt in H(2)O/DMF (DMF is dimethyl­formamide), is composed of a chain of [Mn(2)(BIDPE)(2)] [BIDPE is 1,1′-(oxydi-p-phenyl­ene)di-1H-imidazole] metallocyclic rings that exhibit inversion symmetry. The coordination about the Mn(II) ions is distorted octahedral with a MnClN(4)O coordination set. In the crystal, the polymeric chains are linked by O—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to (100). A number of C—H⋯Cl and C—H⋯O inter­actions are also present.
format Text
id pubmed-3051568
institution National Center for Biotechnology Information
language English
publishDate 2011
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-30515682011-04-26 catena-Poly[[[aqua­chlorido­manganese(II)]-bis­[μ-1,1′-(oxydi-p-phenyl­ene)di-1H-imidazole-κ(2) N (3):N (3′)]] chloride dimethyl­formamide mono­solvate monohydrate] Mu, Xiao-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title coordination polymer, {[MnCl(C(18)H(14)N(4)O)(2)(H(2)O)]Cl·C(3)H(7)NO·H(2)O}(n), obtained by the solvothermal reaction of BIDPE and manganese(II) salt in H(2)O/DMF (DMF is dimethyl­formamide), is composed of a chain of [Mn(2)(BIDPE)(2)] [BIDPE is 1,1′-(oxydi-p-phenyl­ene)di-1H-imidazole] metallocyclic rings that exhibit inversion symmetry. The coordination about the Mn(II) ions is distorted octahedral with a MnClN(4)O coordination set. In the crystal, the polymeric chains are linked by O—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to (100). A number of C—H⋯Cl and C—H⋯O inter­actions are also present. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051568/ /pubmed/21522845 http://dx.doi.org/10.1107/S1600536810054383 Text en © Xiao-Long Mu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Mu, Xiao-Long
catena-Poly[[[aqua­chlorido­manganese(II)]-bis­[μ-1,1′-(oxydi-p-phenyl­ene)di-1H-imidazole-κ(2) N (3):N (3′)]] chloride dimethyl­formamide mono­solvate monohydrate]
title catena-Poly[[[aqua­chlorido­manganese(II)]-bis­[μ-1,1′-(oxydi-p-phenyl­ene)di-1H-imidazole-κ(2) N (3):N (3′)]] chloride dimethyl­formamide mono­solvate monohydrate]
title_full catena-Poly[[[aqua­chlorido­manganese(II)]-bis­[μ-1,1′-(oxydi-p-phenyl­ene)di-1H-imidazole-κ(2) N (3):N (3′)]] chloride dimethyl­formamide mono­solvate monohydrate]
title_fullStr catena-Poly[[[aqua­chlorido­manganese(II)]-bis­[μ-1,1′-(oxydi-p-phenyl­ene)di-1H-imidazole-κ(2) N (3):N (3′)]] chloride dimethyl­formamide mono­solvate monohydrate]
title_full_unstemmed catena-Poly[[[aqua­chlorido­manganese(II)]-bis­[μ-1,1′-(oxydi-p-phenyl­ene)di-1H-imidazole-κ(2) N (3):N (3′)]] chloride dimethyl­formamide mono­solvate monohydrate]
title_short catena-Poly[[[aqua­chlorido­manganese(II)]-bis­[μ-1,1′-(oxydi-p-phenyl­ene)di-1H-imidazole-κ(2) N (3):N (3′)]] chloride dimethyl­formamide mono­solvate monohydrate]
title_sort catena-poly[[[aqua­chlorido­manganese(ii)]-bis­[μ-1,1′-(oxydi-p-phenyl­ene)di-1h-imidazole-κ(2) n (3):n (3′)]] chloride dimethyl­formamide mono­solvate monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051568/
https://www.ncbi.nlm.nih.gov/pubmed/21522845
http://dx.doi.org/10.1107/S1600536810054383
work_keys_str_mv AT muxiaolong catenapolyaquachloridomanganeseiibism11oxydipphenylenedi1himidazolek2n3n3chloridedimethylformamidemonosolvatemonohydrate