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catena-Poly[[[aquachloridomanganese(II)]-bis[μ-1,1′-(oxydi-p-phenylene)di-1H-imidazole-κ(2) N (3):N (3′)]] chloride dimethylformamide monosolvate monohydrate]
The title coordination polymer, {[MnCl(C(18)H(14)N(4)O)(2)(H(2)O)]Cl·C(3)H(7)NO·H(2)O}(n), obtained by the solvothermal reaction of BIDPE and manganese(II) salt in H(2)O/DMF (DMF is dimethylformamide), is composed of a chain of [Mn(2)(BIDPE)(2)] [BIDPE is 1,1′-(oxydi-p-phenylene)di-1H-imidazole] m...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051568/ https://www.ncbi.nlm.nih.gov/pubmed/21522845 http://dx.doi.org/10.1107/S1600536810054383 |
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author | Mu, Xiao-Long |
author_facet | Mu, Xiao-Long |
author_sort | Mu, Xiao-Long |
collection | PubMed |
description | The title coordination polymer, {[MnCl(C(18)H(14)N(4)O)(2)(H(2)O)]Cl·C(3)H(7)NO·H(2)O}(n), obtained by the solvothermal reaction of BIDPE and manganese(II) salt in H(2)O/DMF (DMF is dimethylformamide), is composed of a chain of [Mn(2)(BIDPE)(2)] [BIDPE is 1,1′-(oxydi-p-phenylene)di-1H-imidazole] metallocyclic rings that exhibit inversion symmetry. The coordination about the Mn(II) ions is distorted octahedral with a MnClN(4)O coordination set. In the crystal, the polymeric chains are linked by O—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to (100). A number of C—H⋯Cl and C—H⋯O interactions are also present. |
format | Text |
id | pubmed-3051568 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30515682011-04-26 catena-Poly[[[aquachloridomanganese(II)]-bis[μ-1,1′-(oxydi-p-phenylene)di-1H-imidazole-κ(2) N (3):N (3′)]] chloride dimethylformamide monosolvate monohydrate] Mu, Xiao-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title coordination polymer, {[MnCl(C(18)H(14)N(4)O)(2)(H(2)O)]Cl·C(3)H(7)NO·H(2)O}(n), obtained by the solvothermal reaction of BIDPE and manganese(II) salt in H(2)O/DMF (DMF is dimethylformamide), is composed of a chain of [Mn(2)(BIDPE)(2)] [BIDPE is 1,1′-(oxydi-p-phenylene)di-1H-imidazole] metallocyclic rings that exhibit inversion symmetry. The coordination about the Mn(II) ions is distorted octahedral with a MnClN(4)O coordination set. In the crystal, the polymeric chains are linked by O—H⋯Cl hydrogen bonds, forming a two-dimensional network parallel to (100). A number of C—H⋯Cl and C—H⋯O interactions are also present. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051568/ /pubmed/21522845 http://dx.doi.org/10.1107/S1600536810054383 Text en © Xiao-Long Mu 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Mu, Xiao-Long catena-Poly[[[aquachloridomanganese(II)]-bis[μ-1,1′-(oxydi-p-phenylene)di-1H-imidazole-κ(2) N (3):N (3′)]] chloride dimethylformamide monosolvate monohydrate] |
title |
catena-Poly[[[aquachloridomanganese(II)]-bis[μ-1,1′-(oxydi-p-phenylene)di-1H-imidazole-κ(2)
N
(3):N
(3′)]] chloride dimethylformamide monosolvate monohydrate] |
title_full |
catena-Poly[[[aquachloridomanganese(II)]-bis[μ-1,1′-(oxydi-p-phenylene)di-1H-imidazole-κ(2)
N
(3):N
(3′)]] chloride dimethylformamide monosolvate monohydrate] |
title_fullStr |
catena-Poly[[[aquachloridomanganese(II)]-bis[μ-1,1′-(oxydi-p-phenylene)di-1H-imidazole-κ(2)
N
(3):N
(3′)]] chloride dimethylformamide monosolvate monohydrate] |
title_full_unstemmed |
catena-Poly[[[aquachloridomanganese(II)]-bis[μ-1,1′-(oxydi-p-phenylene)di-1H-imidazole-κ(2)
N
(3):N
(3′)]] chloride dimethylformamide monosolvate monohydrate] |
title_short |
catena-Poly[[[aquachloridomanganese(II)]-bis[μ-1,1′-(oxydi-p-phenylene)di-1H-imidazole-κ(2)
N
(3):N
(3′)]] chloride dimethylformamide monosolvate monohydrate] |
title_sort | catena-poly[[[aquachloridomanganese(ii)]-bis[μ-1,1′-(oxydi-p-phenylene)di-1h-imidazole-κ(2)
n
(3):n
(3′)]] chloride dimethylformamide monosolvate monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051568/ https://www.ncbi.nlm.nih.gov/pubmed/21522845 http://dx.doi.org/10.1107/S1600536810054383 |
work_keys_str_mv | AT muxiaolong catenapolyaquachloridomanganeseiibism11oxydipphenylenedi1himidazolek2n3n3chloridedimethylformamidemonosolvatemonohydrate |