6-Cyclo­hexyl-6,7-dihydro­dibenzo[c,f][1,5]aza­bis­mocin-12(5H)-yl(N→Bi) trifluoro­methane­sulfonate

In the title compound, [Bi(C(20)H(23)N)(CF(3)SO(3))], the Bi(III) ion shows a distorted pseudo-trigonal–bipyramidal geometry, with two C atoms and a lone electron pair of the Bi atom in equatorial positions and the N and O atoms at the apical positions. The cyclo­hexyl group is disordered over two o...

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Detalles Bibliográficos
Autores principales: Tan, Nianyuan, Zhang, Xiaowen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051572/
https://www.ncbi.nlm.nih.gov/pubmed/21522906
http://dx.doi.org/10.1107/S1600536811002510
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author Tan, Nianyuan
Zhang, Xiaowen
author_facet Tan, Nianyuan
Zhang, Xiaowen
author_sort Tan, Nianyuan
collection PubMed
description In the title compound, [Bi(C(20)H(23)N)(CF(3)SO(3))], the Bi(III) ion shows a distorted pseudo-trigonal–bipyramidal geometry, with two C atoms and a lone electron pair of the Bi atom in equatorial positions and the N and O atoms at the apical positions. The cyclo­hexyl group is disordered over two orientations with site-occupancy factors of 0.600 (14) and 0.400 (14).
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spelling pubmed-30515722011-04-26 6-Cyclo­hexyl-6,7-dihydro­dibenzo[c,f][1,5]aza­bis­mocin-12(5H)-yl(N→Bi) trifluoro­methane­sulfonate Tan, Nianyuan Zhang, Xiaowen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Bi(C(20)H(23)N)(CF(3)SO(3))], the Bi(III) ion shows a distorted pseudo-trigonal–bipyramidal geometry, with two C atoms and a lone electron pair of the Bi atom in equatorial positions and the N and O atoms at the apical positions. The cyclo­hexyl group is disordered over two orientations with site-occupancy factors of 0.600 (14) and 0.400 (14). International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051572/ /pubmed/21522906 http://dx.doi.org/10.1107/S1600536811002510 Text en © Tan and Zhang 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tan, Nianyuan
Zhang, Xiaowen
6-Cyclo­hexyl-6,7-dihydro­dibenzo[c,f][1,5]aza­bis­mocin-12(5H)-yl(N→Bi) trifluoro­methane­sulfonate
title 6-Cyclo­hexyl-6,7-dihydro­dibenzo[c,f][1,5]aza­bis­mocin-12(5H)-yl(N→Bi) trifluoro­methane­sulfonate
title_full 6-Cyclo­hexyl-6,7-dihydro­dibenzo[c,f][1,5]aza­bis­mocin-12(5H)-yl(N→Bi) trifluoro­methane­sulfonate
title_fullStr 6-Cyclo­hexyl-6,7-dihydro­dibenzo[c,f][1,5]aza­bis­mocin-12(5H)-yl(N→Bi) trifluoro­methane­sulfonate
title_full_unstemmed 6-Cyclo­hexyl-6,7-dihydro­dibenzo[c,f][1,5]aza­bis­mocin-12(5H)-yl(N→Bi) trifluoro­methane­sulfonate
title_short 6-Cyclo­hexyl-6,7-dihydro­dibenzo[c,f][1,5]aza­bis­mocin-12(5H)-yl(N→Bi) trifluoro­methane­sulfonate
title_sort 6-cyclo­hexyl-6,7-dihydro­dibenzo[c,f][1,5]aza­bis­mocin-12(5h)-yl(n→bi) trifluoro­methane­sulfonate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051572/
https://www.ncbi.nlm.nih.gov/pubmed/21522906
http://dx.doi.org/10.1107/S1600536811002510
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AT zhangxiaowen 6cyclohexyl67dihydrodibenzocf15azabismocin125hylnbitrifluoromethanesulfonate

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