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Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis­[(methanol)tris­(nitrato-κ(2) O,O′)terbium(III)]

In the centrosymmetric dinuclear title complex, [Tb(2)(NO(3))(6)(C(10)H(8)N(2)O(2))(2)(CH(3)OH)(2)], the Tb atoms are bridged by the carboxyl­ate groups of the two 4-(1H-imidazol-3-ium-1-yl)benzoate (iba) ligands. The iba ligand adopts a zwitterionic form with a protonated imidazole group. The Tb at...

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Detalles Bibliográficos
Autores principales: Jung, Yeong-Min, Lee, Soon W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051581/
https://www.ncbi.nlm.nih.gov/pubmed/21522907
http://dx.doi.org/10.1107/S1600536811002443
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author Jung, Yeong-Min
Lee, Soon W.
author_facet Jung, Yeong-Min
Lee, Soon W.
author_sort Jung, Yeong-Min
collection PubMed
description In the centrosymmetric dinuclear title complex, [Tb(2)(NO(3))(6)(C(10)H(8)N(2)O(2))(2)(CH(3)OH)(2)], the Tb atoms are bridged by the carboxyl­ate groups of the two 4-(1H-imidazol-3-ium-1-yl)benzoate (iba) ligands. The iba ligand adopts a zwitterionic form with a protonated imidazole group. The Tb atom adopts a distorted tricapped trigonal–prismatic coordination geometry and is coordinated by six O atoms of three chelating nitrate ions, one O atom of the methanol mol­ecule and two O atoms of two iba ligands. The intra­molecular Tb⋯Tb separation is 5.1419 (3) Å. O—H⋯O and N—H⋯O hydrogen bonds connect complex mol­ecules into a two-dimensional network.
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spelling pubmed-30515812011-04-26 Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis­[(methanol)tris­(nitrato-κ(2) O,O′)terbium(III)] Jung, Yeong-Min Lee, Soon W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title complex, [Tb(2)(NO(3))(6)(C(10)H(8)N(2)O(2))(2)(CH(3)OH)(2)], the Tb atoms are bridged by the carboxyl­ate groups of the two 4-(1H-imidazol-3-ium-1-yl)benzoate (iba) ligands. The iba ligand adopts a zwitterionic form with a protonated imidazole group. The Tb atom adopts a distorted tricapped trigonal–prismatic coordination geometry and is coordinated by six O atoms of three chelating nitrate ions, one O atom of the methanol mol­ecule and two O atoms of two iba ligands. The intra­molecular Tb⋯Tb separation is 5.1419 (3) Å. O—H⋯O and N—H⋯O hydrogen bonds connect complex mol­ecules into a two-dimensional network. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051581/ /pubmed/21522907 http://dx.doi.org/10.1107/S1600536811002443 Text en © Jung and Lee 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jung, Yeong-Min
Lee, Soon W.
Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis­[(methanol)tris­(nitrato-κ(2) O,O′)terbium(III)]
title Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis­[(methanol)tris­(nitrato-κ(2) O,O′)terbium(III)]
title_full Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis­[(methanol)tris­(nitrato-κ(2) O,O′)terbium(III)]
title_fullStr Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis­[(methanol)tris­(nitrato-κ(2) O,O′)terbium(III)]
title_full_unstemmed Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis­[(methanol)tris­(nitrato-κ(2) O,O′)terbium(III)]
title_short Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis­[(methanol)tris­(nitrato-κ(2) O,O′)terbium(III)]
title_sort bis[μ-4-(1h-imidazol-3-ium-1-yl)benzoato-κ(2) o:o′]bis­[(methanol)tris­(nitrato-κ(2) o,o′)terbium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051581/
https://www.ncbi.nlm.nih.gov/pubmed/21522907
http://dx.doi.org/10.1107/S1600536811002443
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