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Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis[(methanol)tris(nitrato-κ(2) O,O′)terbium(III)]
In the centrosymmetric dinuclear title complex, [Tb(2)(NO(3))(6)(C(10)H(8)N(2)O(2))(2)(CH(3)OH)(2)], the Tb atoms are bridged by the carboxylate groups of the two 4-(1H-imidazol-3-ium-1-yl)benzoate (iba) ligands. The iba ligand adopts a zwitterionic form with a protonated imidazole group. The Tb at...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051581/ https://www.ncbi.nlm.nih.gov/pubmed/21522907 http://dx.doi.org/10.1107/S1600536811002443 |
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author | Jung, Yeong-Min Lee, Soon W. |
author_facet | Jung, Yeong-Min Lee, Soon W. |
author_sort | Jung, Yeong-Min |
collection | PubMed |
description | In the centrosymmetric dinuclear title complex, [Tb(2)(NO(3))(6)(C(10)H(8)N(2)O(2))(2)(CH(3)OH)(2)], the Tb atoms are bridged by the carboxylate groups of the two 4-(1H-imidazol-3-ium-1-yl)benzoate (iba) ligands. The iba ligand adopts a zwitterionic form with a protonated imidazole group. The Tb atom adopts a distorted tricapped trigonal–prismatic coordination geometry and is coordinated by six O atoms of three chelating nitrate ions, one O atom of the methanol molecule and two O atoms of two iba ligands. The intramolecular Tb⋯Tb separation is 5.1419 (3) Å. O—H⋯O and N—H⋯O hydrogen bonds connect complex molecules into a two-dimensional network. |
format | Text |
id | pubmed-3051581 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30515812011-04-26 Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis[(methanol)tris(nitrato-κ(2) O,O′)terbium(III)] Jung, Yeong-Min Lee, Soon W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title complex, [Tb(2)(NO(3))(6)(C(10)H(8)N(2)O(2))(2)(CH(3)OH)(2)], the Tb atoms are bridged by the carboxylate groups of the two 4-(1H-imidazol-3-ium-1-yl)benzoate (iba) ligands. The iba ligand adopts a zwitterionic form with a protonated imidazole group. The Tb atom adopts a distorted tricapped trigonal–prismatic coordination geometry and is coordinated by six O atoms of three chelating nitrate ions, one O atom of the methanol molecule and two O atoms of two iba ligands. The intramolecular Tb⋯Tb separation is 5.1419 (3) Å. O—H⋯O and N—H⋯O hydrogen bonds connect complex molecules into a two-dimensional network. International Union of Crystallography 2011-01-22 /pmc/articles/PMC3051581/ /pubmed/21522907 http://dx.doi.org/10.1107/S1600536811002443 Text en © Jung and Lee 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Jung, Yeong-Min Lee, Soon W. Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2) O:O′]bis[(methanol)tris(nitrato-κ(2) O,O′)terbium(III)] |
title | Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2)
O:O′]bis[(methanol)tris(nitrato-κ(2)
O,O′)terbium(III)] |
title_full | Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2)
O:O′]bis[(methanol)tris(nitrato-κ(2)
O,O′)terbium(III)] |
title_fullStr | Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2)
O:O′]bis[(methanol)tris(nitrato-κ(2)
O,O′)terbium(III)] |
title_full_unstemmed | Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2)
O:O′]bis[(methanol)tris(nitrato-κ(2)
O,O′)terbium(III)] |
title_short | Bis[μ-4-(1H-imidazol-3-ium-1-yl)benzoato-κ(2)
O:O′]bis[(methanol)tris(nitrato-κ(2)
O,O′)terbium(III)] |
title_sort | bis[μ-4-(1h-imidazol-3-ium-1-yl)benzoato-κ(2)
o:o′]bis[(methanol)tris(nitrato-κ(2)
o,o′)terbium(iii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051581/ https://www.ncbi.nlm.nih.gov/pubmed/21522907 http://dx.doi.org/10.1107/S1600536811002443 |
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