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[μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl­stibine-3κSb)-triangulo-triruthenium(0)

The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(26)H(24)P(2))(C(18)H(15)Sb)(CO)(9)], consists of two crystallographically independent mol­ecules, A and B. The bis­(diphenyl­phosphan­yl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the thir...

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Autores principales: Shawkataly, Omar bin, Khan, Imthyaz Ahmed, Sirat, Siti Syaida, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051588/
https://www.ncbi.nlm.nih.gov/pubmed/21522852
http://dx.doi.org/10.1107/S1600536810054218
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author Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Sirat, Siti Syaida
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Sirat, Siti Syaida
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Shawkataly, Omar bin
collection PubMed
description The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(26)H(24)P(2))(C(18)H(15)Sb)(CO)(9)], consists of two crystallographically independent mol­ecules, A and B. The bis­(diphenyl­phosphan­yl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and phosphine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted benzene rings make dihedral angles of 38.7 (3), 71.5 (3) and 70.0 (3)° with each other in mol­ecule A whereas these angles are 83.9 (3), 88.2 (3) and 56.8 (3)° in mol­ecule B. Similarly, the dihedral angles between the two benzene rings are 80.7 (3) and 87.6 (3)° for the two diphenyl­phosphanyl groups in mol­ecule A and 84.0 (3) and 72.6 (4)° in mol­ecule B. In the crystal, mol­ecules are linked into tetra­mers via inter­molecular C—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯π inter­actions further stabilize the crystal structure.
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spelling pubmed-30515882011-04-26 [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl­stibine-3κSb)-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(26)H(24)P(2))(C(18)H(15)Sb)(CO)(9)], consists of two crystallographically independent mol­ecules, A and B. The bis­(diphenyl­phosphan­yl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and phosphine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted benzene rings make dihedral angles of 38.7 (3), 71.5 (3) and 70.0 (3)° with each other in mol­ecule A whereas these angles are 83.9 (3), 88.2 (3) and 56.8 (3)° in mol­ecule B. Similarly, the dihedral angles between the two benzene rings are 80.7 (3) and 87.6 (3)° for the two diphenyl­phosphanyl groups in mol­ecule A and 84.0 (3) and 72.6 (4)° in mol­ecule B. In the crystal, mol­ecules are linked into tetra­mers via inter­molecular C—H⋯O hydrogen bonds. Weak inter­molecular C—H⋯π inter­actions further stabilize the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051588/ /pubmed/21522852 http://dx.doi.org/10.1107/S1600536810054218 Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shawkataly, Omar bin
Khan, Imthyaz Ahmed
Sirat, Siti Syaida
Yeap, Chin Sing
Fun, Hoong-Kun
[μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl­stibine-3κSb)-triangulo-triruthenium(0)
title [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl­stibine-3κSb)-triangulo-triruthenium(0)
title_full [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl­stibine-3κSb)-triangulo-triruthenium(0)
title_fullStr [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl­stibine-3κSb)-triangulo-triruthenium(0)
title_full_unstemmed [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl­stibine-3κSb)-triangulo-triruthenium(0)
title_short [μ-Bis(diphenyl­phosphan­yl)ethane-1:2κ(2) P:P′]nona­carbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenyl­stibine-3κSb)-triangulo-triruthenium(0)
title_sort [μ-bis(diphenyl­phosphan­yl)ethane-1:2κ(2) p:p′]nona­carbonyl-1κ(3) c,2κ(3) c,3κ(3) c-(triphenyl­stibine-3κsb)-triangulo-triruthenium(0)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051588/
https://www.ncbi.nlm.nih.gov/pubmed/21522852
http://dx.doi.org/10.1107/S1600536810054218
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