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[μ-Bis(diphenylphosphanyl)ethane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenylstibine-3κSb)-triangulo-triruthenium(0)
The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(26)H(24)P(2))(C(18)H(15)Sb)(CO)(9)], consists of two crystallographically independent molecules, A and B. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the thir...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051588/ https://www.ncbi.nlm.nih.gov/pubmed/21522852 http://dx.doi.org/10.1107/S1600536810054218 |
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author | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun |
author_facet | Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun |
author_sort | Shawkataly, Omar bin |
collection | PubMed |
description | The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(26)H(24)P(2))(C(18)H(15)Sb)(CO)(9)], consists of two crystallographically independent molecules, A and B. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and phosphine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted benzene rings make dihedral angles of 38.7 (3), 71.5 (3) and 70.0 (3)° with each other in molecule A whereas these angles are 83.9 (3), 88.2 (3) and 56.8 (3)° in molecule B. Similarly, the dihedral angles between the two benzene rings are 80.7 (3) and 87.6 (3)° for the two diphenylphosphanyl groups in molecule A and 84.0 (3) and 72.6 (4)° in molecule B. In the crystal, molecules are linked into tetramers via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure. |
format | Text |
id | pubmed-3051588 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30515882011-04-26 [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(26)H(24)P(2))(C(18)H(15)Sb)(CO)(9)], consists of two crystallographically independent molecules, A and B. The bis(diphenylphosphanyl)ethane ligand bridges an Ru—Ru bond and the monodentate stibine ligand bonds to the third Ru atom. Both the stibine and phosphine ligands are equatorial with respect to the Ru(3) triangle. Additionally, each Ru atom carries one equatorial and two axial terminal carbonyl ligands. The three stibine-substituted benzene rings make dihedral angles of 38.7 (3), 71.5 (3) and 70.0 (3)° with each other in molecule A whereas these angles are 83.9 (3), 88.2 (3) and 56.8 (3)° in molecule B. Similarly, the dihedral angles between the two benzene rings are 80.7 (3) and 87.6 (3)° for the two diphenylphosphanyl groups in molecule A and 84.0 (3) and 72.6 (4)° in molecule B. In the crystal, molecules are linked into tetramers via intermolecular C—H⋯O hydrogen bonds. Weak intermolecular C—H⋯π interactions further stabilize the crystal structure. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051588/ /pubmed/21522852 http://dx.doi.org/10.1107/S1600536810054218 Text en © Shawkataly et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shawkataly, Omar bin Khan, Imthyaz Ahmed Sirat, Siti Syaida Yeap, Chin Sing Fun, Hoong-Kun [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2) P:P′]nonacarbonyl-1κ(3) C,2κ(3) C,3κ(3) C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) |
title | [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) |
title_full | [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) |
title_fullStr | [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) |
title_full_unstemmed | [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) |
title_short | [μ-Bis(diphenylphosphanyl)ethane-1:2κ(2)
P:P′]nonacarbonyl-1κ(3)
C,2κ(3)
C,3κ(3)
C-(triphenylstibine-3κSb)-triangulo-triruthenium(0) |
title_sort | [μ-bis(diphenylphosphanyl)ethane-1:2κ(2)
p:p′]nonacarbonyl-1κ(3)
c,2κ(3)
c,3κ(3)
c-(triphenylstibine-3κsb)-triangulo-triruthenium(0) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051588/ https://www.ncbi.nlm.nih.gov/pubmed/21522852 http://dx.doi.org/10.1107/S1600536810054218 |
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