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4-Bromo-2-{[(pyridin-3-ylmethyl)imino]methyl}phenol
The title compound, C(13)H(11)BrN(2)O, is a polydentate Schiff base and reveals intramolecular O—H⋯N hydrogen bonding between the hydroxy O atom and the imino N atom. The dihedral angle between the aromatic ring and the pyridyl ring is 71.7 (1)°. In the crystal, the molecules are stacked in colum...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2011
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051591/ https://www.ncbi.nlm.nih.gov/pubmed/21523168 http://dx.doi.org/10.1107/S1600536811003011 |
Sumario: | The title compound, C(13)H(11)BrN(2)O, is a polydentate Schiff base and reveals intramolecular O—H⋯N hydrogen bonding between the hydroxy O atom and the imino N atom. The dihedral angle between the aromatic ring and the pyridyl ring is 71.7 (1)°. In the crystal, the molecules are stacked in columns along the c axis and several intermolecular π–π interactions are present between the six-membered rings, with a shortest centroid–centroid distance of 3.707 (2) Å. |
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