4-Bromo-2-{[(pyridin-3-ylmeth­yl)imino]­meth­yl}phenol

The title compound, C(13)H(11)BrN(2)O, is a polydentate Schiff base and reveals intra­molecular O—H⋯N hydrogen bonding between the hy­droxy O atom and the imino N atom. The dihedral angle between the aromatic ring and the pyridyl ring is 71.7 (1)°. In the crystal, the mol­ecules are stacked in colum...

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Detalles Bibliográficos
Autor principal: Ha, Kwang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051591/
https://www.ncbi.nlm.nih.gov/pubmed/21523168
http://dx.doi.org/10.1107/S1600536811003011
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author Ha, Kwang
author_facet Ha, Kwang
author_sort Ha, Kwang
collection PubMed
description The title compound, C(13)H(11)BrN(2)O, is a polydentate Schiff base and reveals intra­molecular O—H⋯N hydrogen bonding between the hy­droxy O atom and the imino N atom. The dihedral angle between the aromatic ring and the pyridyl ring is 71.7 (1)°. In the crystal, the mol­ecules are stacked in columns along the c axis and several inter­molecular π–π inter­actions are present between the six-membered rings, with a shortest centroid–centroid distance of 3.707 (2) Å.
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spelling pubmed-30515912011-04-26 4-Bromo-2-{[(pyridin-3-ylmeth­yl)imino]­meth­yl}phenol Ha, Kwang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(11)BrN(2)O, is a polydentate Schiff base and reveals intra­molecular O—H⋯N hydrogen bonding between the hy­droxy O atom and the imino N atom. The dihedral angle between the aromatic ring and the pyridyl ring is 71.7 (1)°. In the crystal, the mol­ecules are stacked in columns along the c axis and several inter­molecular π–π inter­actions are present between the six-membered rings, with a shortest centroid–centroid distance of 3.707 (2) Å. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051591/ /pubmed/21523168 http://dx.doi.org/10.1107/S1600536811003011 Text en © Kwang Ha 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ha, Kwang
4-Bromo-2-{[(pyridin-3-ylmeth­yl)imino]­meth­yl}phenol
title 4-Bromo-2-{[(pyridin-3-ylmeth­yl)imino]­meth­yl}phenol
title_full 4-Bromo-2-{[(pyridin-3-ylmeth­yl)imino]­meth­yl}phenol
title_fullStr 4-Bromo-2-{[(pyridin-3-ylmeth­yl)imino]­meth­yl}phenol
title_full_unstemmed 4-Bromo-2-{[(pyridin-3-ylmeth­yl)imino]­meth­yl}phenol
title_short 4-Bromo-2-{[(pyridin-3-ylmeth­yl)imino]­meth­yl}phenol
title_sort 4-bromo-2-{[(pyridin-3-ylmeth­yl)imino]­meth­yl}phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051591/
https://www.ncbi.nlm.nih.gov/pubmed/21523168
http://dx.doi.org/10.1107/S1600536811003011
work_keys_str_mv AT hakwang 4bromo2pyridin3ylmethyliminomethylphenol

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