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Monoclinic modification of bis(μ(2)-pyridine-2,6-dicarboxylato)-κ(4) O (2),N,O (6):O (6);κ(4) O (2):O (2),N,O (6)-bis[aquadibutyltin(IV)]
The Sn(IV) atom in the centrosymmetric dinuclear title compound, [Sn(2)(C(4)H(9))(4)(C(7)H(3)NO(4))(2)(H(2)O)(2)], exists in a trans-C(2)SnNO(4) pentagonal–bipyramidal geometry. There are two half-molecules in the asymmetric unit that are completed by inversion symmetry. The crystal studied was a...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051593/ https://www.ncbi.nlm.nih.gov/pubmed/21522924 http://dx.doi.org/10.1107/S1600536811002935 |
Sumario: | The Sn(IV) atom in the centrosymmetric dinuclear title compound, [Sn(2)(C(4)H(9))(4)(C(7)H(3)NO(4))(2)(H(2)O)(2)], exists in a trans-C(2)SnNO(4) pentagonal–bipyramidal geometry. There are two half-molecules in the asymmetric unit that are completed by inversion symmetry. The crystal studied was a non-merohedral twin with a ratio of 47.3 (1)% for the minor twin component. Bond dimensions are similar to those found in the tetragonal polymorph [Huber et al. (1989 ▶). Acta Cryst. C45, 51–54]. O—H⋯O hydrogen-bonding interactions stabilize the crystal packing. |
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