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Monoclinic modification of bis(μ(2)-pyridine-2,6-dicarboxylato)-κ(4) O (2),N,O (6):O (6);κ(4) O (2):O (2),N,O (6)-bis[aquadibutyltin(IV)]
The Sn(IV) atom in the centrosymmetric dinuclear title compound, [Sn(2)(C(4)H(9))(4)(C(7)H(3)NO(4))(2)(H(2)O)(2)], exists in a trans-C(2)SnNO(4) pentagonal–bipyramidal geometry. There are two half-molecules in the asymmetric unit that are completed by inversion symmetry. The crystal studied was a...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051593/ https://www.ncbi.nlm.nih.gov/pubmed/21522924 http://dx.doi.org/10.1107/S1600536811002935 |
| _version_ | 1782199515899494400 |
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| author | Ng, Seik Weng |
| author_facet | Ng, Seik Weng |
| author_sort | Ng, Seik Weng |
| collection | PubMed |
| description | The Sn(IV) atom in the centrosymmetric dinuclear title compound, [Sn(2)(C(4)H(9))(4)(C(7)H(3)NO(4))(2)(H(2)O)(2)], exists in a trans-C(2)SnNO(4) pentagonal–bipyramidal geometry. There are two half-molecules in the asymmetric unit that are completed by inversion symmetry. The crystal studied was a non-merohedral twin with a ratio of 47.3 (1)% for the minor twin component. Bond dimensions are similar to those found in the tetragonal polymorph [Huber et al. (1989 ▶). Acta Cryst. C45, 51–54]. O—H⋯O hydrogen-bonding interactions stabilize the crystal packing. |
| format | Text |
| id | pubmed-3051593 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30515932011-04-26 Monoclinic modification of bis(μ(2)-pyridine-2,6-dicarboxylato)-κ(4) O (2),N,O (6):O (6);κ(4) O (2):O (2),N,O (6)-bis[aquadibutyltin(IV)] Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn(IV) atom in the centrosymmetric dinuclear title compound, [Sn(2)(C(4)H(9))(4)(C(7)H(3)NO(4))(2)(H(2)O)(2)], exists in a trans-C(2)SnNO(4) pentagonal–bipyramidal geometry. There are two half-molecules in the asymmetric unit that are completed by inversion symmetry. The crystal studied was a non-merohedral twin with a ratio of 47.3 (1)% for the minor twin component. Bond dimensions are similar to those found in the tetragonal polymorph [Huber et al. (1989 ▶). Acta Cryst. C45, 51–54]. O—H⋯O hydrogen-bonding interactions stabilize the crystal packing. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051593/ /pubmed/21522924 http://dx.doi.org/10.1107/S1600536811002935 Text en © Seik Weng Ng 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Ng, Seik Weng Monoclinic modification of bis(μ(2)-pyridine-2,6-dicarboxylato)-κ(4) O (2),N,O (6):O (6);κ(4) O (2):O (2),N,O (6)-bis[aquadibutyltin(IV)] |
| title | Monoclinic modification of bis(μ(2)-pyridine-2,6-dicarboxylato)-κ(4)
O
(2),N,O
(6):O
(6);κ(4)
O
(2):O
(2),N,O
(6)-bis[aquadibutyltin(IV)] |
| title_full | Monoclinic modification of bis(μ(2)-pyridine-2,6-dicarboxylato)-κ(4)
O
(2),N,O
(6):O
(6);κ(4)
O
(2):O
(2),N,O
(6)-bis[aquadibutyltin(IV)] |
| title_fullStr | Monoclinic modification of bis(μ(2)-pyridine-2,6-dicarboxylato)-κ(4)
O
(2),N,O
(6):O
(6);κ(4)
O
(2):O
(2),N,O
(6)-bis[aquadibutyltin(IV)] |
| title_full_unstemmed | Monoclinic modification of bis(μ(2)-pyridine-2,6-dicarboxylato)-κ(4)
O
(2),N,O
(6):O
(6);κ(4)
O
(2):O
(2),N,O
(6)-bis[aquadibutyltin(IV)] |
| title_short | Monoclinic modification of bis(μ(2)-pyridine-2,6-dicarboxylato)-κ(4)
O
(2),N,O
(6):O
(6);κ(4)
O
(2):O
(2),N,O
(6)-bis[aquadibutyltin(IV)] |
| title_sort | monoclinic modification of bis(μ(2)-pyridine-2,6-dicarboxylato)-κ(4)
o
(2),n,o
(6):o
(6);κ(4)
o
(2):o
(2),n,o
(6)-bis[aquadibutyltin(iv)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051593/ https://www.ncbi.nlm.nih.gov/pubmed/21522924 http://dx.doi.org/10.1107/S1600536811002935 |
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