[5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato-κ(4) N,N′,N′′,N′′′](trifluoro­methane­sulfonato-κO)­iron(III)

The title compound, [Fe(CF(3)O(3)S)(C(48)H(36)N(4)O(4))], is a five-coordinate iron(III) porphyrin complex with a trifluoro­methane­sulfonate anion as an axial ligand. The Fe(III) atom is displaced by 0.40 (1) Å towards the trifluoro­methane­sulfonate anion from the 24-atom mean plane of the porphyr...

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Detalles Bibliográficos
Autores principales: Xu, Nan, Powell, Douglas R., Richter-Addo, George B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051595/
https://www.ncbi.nlm.nih.gov/pubmed/21522918
http://dx.doi.org/10.1107/S1600536811001395
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author Xu, Nan
Powell, Douglas R.
Richter-Addo, George B.
author_facet Xu, Nan
Powell, Douglas R.
Richter-Addo, George B.
author_sort Xu, Nan
collection PubMed
description The title compound, [Fe(CF(3)O(3)S)(C(48)H(36)N(4)O(4))], is a five-coordinate iron(III) porphyrin complex with a trifluoro­methane­sulfonate anion as an axial ligand. The Fe(III) atom is displaced by 0.40 (1) Å towards the trifluoro­methane­sulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe—N(p) distance is 2.044 (2) Å and the Fe—O distance is 2.001 (2) Å.
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spelling pubmed-30515952011-04-26 [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato-κ(4) N,N′,N′′,N′′′](trifluoro­methane­sulfonato-κO)­iron(III) Xu, Nan Powell, Douglas R. Richter-Addo, George B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(CF(3)O(3)S)(C(48)H(36)N(4)O(4))], is a five-coordinate iron(III) porphyrin complex with a trifluoro­methane­sulfonate anion as an axial ligand. The Fe(III) atom is displaced by 0.40 (1) Å towards the trifluoro­methane­sulfonate anion from the 24-atom mean plane of the porphyrin. The average Fe—N(p) distance is 2.044 (2) Å and the Fe—O distance is 2.001 (2) Å. International Union of Crystallography 2011-01-29 /pmc/articles/PMC3051595/ /pubmed/21522918 http://dx.doi.org/10.1107/S1600536811001395 Text en © Xu et al. 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Nan
Powell, Douglas R.
Richter-Addo, George B.
[5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato-κ(4) N,N′,N′′,N′′′](trifluoro­methane­sulfonato-κO)­iron(III)
title [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato-κ(4) N,N′,N′′,N′′′](trifluoro­methane­sulfonato-κO)­iron(III)
title_full [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato-κ(4) N,N′,N′′,N′′′](trifluoro­methane­sulfonato-κO)­iron(III)
title_fullStr [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato-κ(4) N,N′,N′′,N′′′](trifluoro­methane­sulfonato-κO)­iron(III)
title_full_unstemmed [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato-κ(4) N,N′,N′′,N′′′](trifluoro­methane­sulfonato-κO)­iron(III)
title_short [5,10,15,20-Tetra­kis(4-meth­oxy­phen­yl)porphyrinato-κ(4) N,N′,N′′,N′′′](trifluoro­methane­sulfonato-κO)­iron(III)
title_sort [5,10,15,20-tetra­kis(4-meth­oxy­phen­yl)porphyrinato-κ(4) n,n′,n′′,n′′′](trifluoro­methane­sulfonato-κo)­iron(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051595/
https://www.ncbi.nlm.nih.gov/pubmed/21522918
http://dx.doi.org/10.1107/S1600536811001395
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AT richteraddogeorgeb 5101520tetrakis4methoxyphenylporphyrinatok4nnnntrifluoromethanesulfonatokoironiii

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