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2-(1H-Benzimidazol-2-yl)-4-nitro­phenol

The title compound, C(13)H(9)N(3)O(3), was prepared by the reaction of 5-nitro­salicyl­aldehyde with 1,2-diamino­benzene in methanol. The whole mol­ecule is approximately planar, with a mean deviation from the plane defined by the non-H atoms of 0.0311 (4) Å, and with a dihedral angle between the be...

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Detalles Bibliográficos
Autores principales: Sun, Jingya, Tong, Xiangdi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051601/
https://www.ncbi.nlm.nih.gov/pubmed/21523080
http://dx.doi.org/10.1107/S1600536811001644
Descripción
Sumario:The title compound, C(13)H(9)N(3)O(3), was prepared by the reaction of 5-nitro­salicyl­aldehyde with 1,2-diamino­benzene in methanol. The whole mol­ecule is approximately planar, with a mean deviation from the plane defined by the non-H atoms of 0.0311 (4) Å, and with a dihedral angle between the benzene ring and the benzimidazole ring system of 1.1 (3)°. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, adjacent mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds, forming centrosymmetric dimers.