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2-(1H-Benzimidazol-2-yl)-4-nitro­phenol

The title compound, C(13)H(9)N(3)O(3), was prepared by the reaction of 5-nitro­salicyl­aldehyde with 1,2-diamino­benzene in methanol. The whole mol­ecule is approximately planar, with a mean deviation from the plane defined by the non-H atoms of 0.0311 (4) Å, and with a dihedral angle between the be...

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Detalles Bibliográficos
Autores principales: Sun, Jingya, Tong, Xiangdi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051601/
https://www.ncbi.nlm.nih.gov/pubmed/21523080
http://dx.doi.org/10.1107/S1600536811001644
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author Sun, Jingya
Tong, Xiangdi
author_facet Sun, Jingya
Tong, Xiangdi
author_sort Sun, Jingya
collection PubMed
description The title compound, C(13)H(9)N(3)O(3), was prepared by the reaction of 5-nitro­salicyl­aldehyde with 1,2-diamino­benzene in methanol. The whole mol­ecule is approximately planar, with a mean deviation from the plane defined by the non-H atoms of 0.0311 (4) Å, and with a dihedral angle between the benzene ring and the benzimidazole ring system of 1.1 (3)°. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, adjacent mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds, forming centrosymmetric dimers.
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spelling pubmed-30516012011-04-26 2-(1H-Benzimidazol-2-yl)-4-nitro­phenol Sun, Jingya Tong, Xiangdi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(9)N(3)O(3), was prepared by the reaction of 5-nitro­salicyl­aldehyde with 1,2-diamino­benzene in methanol. The whole mol­ecule is approximately planar, with a mean deviation from the plane defined by the non-H atoms of 0.0311 (4) Å, and with a dihedral angle between the benzene ring and the benzimidazole ring system of 1.1 (3)°. An intra­molecular O—H⋯N hydrogen bond occurs. In the crystal, adjacent mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonds, forming centrosymmetric dimers. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051601/ /pubmed/21523080 http://dx.doi.org/10.1107/S1600536811001644 Text en © Sun and Tong 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Jingya
Tong, Xiangdi
2-(1H-Benzimidazol-2-yl)-4-nitro­phenol
title 2-(1H-Benzimidazol-2-yl)-4-nitro­phenol
title_full 2-(1H-Benzimidazol-2-yl)-4-nitro­phenol
title_fullStr 2-(1H-Benzimidazol-2-yl)-4-nitro­phenol
title_full_unstemmed 2-(1H-Benzimidazol-2-yl)-4-nitro­phenol
title_short 2-(1H-Benzimidazol-2-yl)-4-nitro­phenol
title_sort 2-(1h-benzimidazol-2-yl)-4-nitro­phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051601/
https://www.ncbi.nlm.nih.gov/pubmed/21523080
http://dx.doi.org/10.1107/S1600536811001644
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AT tongxiangdi 21hbenzimidazol2yl4nitrophenol