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2-(1H-Benzimidazol-2-yl)-4-nitrophenol
The title compound, C(13)H(9)N(3)O(3), was prepared by the reaction of 5-nitrosalicylaldehyde with 1,2-diaminobenzene in methanol. The whole molecule is approximately planar, with a mean deviation from the plane defined by the non-H atoms of 0.0311 (4) Å, and with a dihedral angle between the be...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2011
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051601/ https://www.ncbi.nlm.nih.gov/pubmed/21523080 http://dx.doi.org/10.1107/S1600536811001644 |
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author | Sun, Jingya Tong, Xiangdi |
author_facet | Sun, Jingya Tong, Xiangdi |
author_sort | Sun, Jingya |
collection | PubMed |
description | The title compound, C(13)H(9)N(3)O(3), was prepared by the reaction of 5-nitrosalicylaldehyde with 1,2-diaminobenzene in methanol. The whole molecule is approximately planar, with a mean deviation from the plane defined by the non-H atoms of 0.0311 (4) Å, and with a dihedral angle between the benzene ring and the benzimidazole ring system of 1.1 (3)°. An intramolecular O—H⋯N hydrogen bond occurs. In the crystal, adjacent molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming centrosymmetric dimers. |
format | Text |
id | pubmed-3051601 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2011 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-30516012011-04-26 2-(1H-Benzimidazol-2-yl)-4-nitrophenol Sun, Jingya Tong, Xiangdi Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(9)N(3)O(3), was prepared by the reaction of 5-nitrosalicylaldehyde with 1,2-diaminobenzene in methanol. The whole molecule is approximately planar, with a mean deviation from the plane defined by the non-H atoms of 0.0311 (4) Å, and with a dihedral angle between the benzene ring and the benzimidazole ring system of 1.1 (3)°. An intramolecular O—H⋯N hydrogen bond occurs. In the crystal, adjacent molecules are linked through intermolecular N—H⋯O hydrogen bonds, forming centrosymmetric dimers. International Union of Crystallography 2011-01-15 /pmc/articles/PMC3051601/ /pubmed/21523080 http://dx.doi.org/10.1107/S1600536811001644 Text en © Sun and Tong 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sun, Jingya Tong, Xiangdi 2-(1H-Benzimidazol-2-yl)-4-nitrophenol |
title | 2-(1H-Benzimidazol-2-yl)-4-nitrophenol |
title_full | 2-(1H-Benzimidazol-2-yl)-4-nitrophenol |
title_fullStr | 2-(1H-Benzimidazol-2-yl)-4-nitrophenol |
title_full_unstemmed | 2-(1H-Benzimidazol-2-yl)-4-nitrophenol |
title_short | 2-(1H-Benzimidazol-2-yl)-4-nitrophenol |
title_sort | 2-(1h-benzimidazol-2-yl)-4-nitrophenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051601/ https://www.ncbi.nlm.nih.gov/pubmed/21523080 http://dx.doi.org/10.1107/S1600536811001644 |
work_keys_str_mv | AT sunjingya 21hbenzimidazol2yl4nitrophenol AT tongxiangdi 21hbenzimidazol2yl4nitrophenol |