(μ-Benzoato-κ(2) O:O′)tris­[μ-N,N′-bis­(4-meth­oxy­phen­yl)formamidinato-κ(2) N:N′]dimolybdenum(II) dichloro­methane monosolvate

The title compound, [Mo(2)(C(15)H(15)N(2)O(2))(3)(C(7)H(5)O(2))]·CH(2)Cl(2), has a quadruply bonded Mo(2) (4+) unit equatorially coordinated by three N,N′-bis­(4-μ-meth­oxy­phen­yl)formamidinate (DAniF) ligands and one benzoate anion. The Mo—Mo bond length of 2.0881 (8) Å is typical for quadruply bo...

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Detalles Bibliográficos
Autor principal: Han, L.-J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2011
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051605/
https://www.ncbi.nlm.nih.gov/pubmed/21522909
http://dx.doi.org/10.1107/S1600536811002558
Descripción
Sumario:The title compound, [Mo(2)(C(15)H(15)N(2)O(2))(3)(C(7)H(5)O(2))]·CH(2)Cl(2), has a quadruply bonded Mo(2) (4+) unit equatorially coordinated by three N,N′-bis­(4-μ-meth­oxy­phen­yl)formamidinate (DAniF) ligands and one benzoate anion. The Mo—Mo bond length of 2.0881 (8) Å is typical for quadruply bonded species. The phenyl ring and the connected dimetal chelating ring (Mo(2)O(2)C) are nearly co-planar, making a dihedral angle of 3.24 (13)°. The dichloromethane solvent molecule is disordered over four sets of sites with occupancies of 0.3:0.3:0.2:0.2.

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