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(μ-Benzoato-κ(2) O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ(2) N:N′]dimolybdenum(II) dichloromethane monosolvate
The title compound, [Mo(2)(C(15)H(15)N(2)O(2))(3)(C(7)H(5)O(2))]·CH(2)Cl(2), has a quadruply bonded Mo(2) (4+) unit equatorially coordinated by three N,N′-bis(4-μ-methoxyphenyl)formamidinate (DAniF) ligands and one benzoate anion. The Mo—Mo bond length of 2.0881 (8) Å is typical for quadruply bo...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2011
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051605/ https://www.ncbi.nlm.nih.gov/pubmed/21522909 http://dx.doi.org/10.1107/S1600536811002558 |
| _version_ | 1782199518718066688 |
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| author | Han, L.-J. |
| author_facet | Han, L.-J. |
| author_sort | Han, L.-J. |
| collection | PubMed |
| description | The title compound, [Mo(2)(C(15)H(15)N(2)O(2))(3)(C(7)H(5)O(2))]·CH(2)Cl(2), has a quadruply bonded Mo(2) (4+) unit equatorially coordinated by three N,N′-bis(4-μ-methoxyphenyl)formamidinate (DAniF) ligands and one benzoate anion. The Mo—Mo bond length of 2.0881 (8) Å is typical for quadruply bonded species. The phenyl ring and the connected dimetal chelating ring (Mo(2)O(2)C) are nearly co-planar, making a dihedral angle of 3.24 (13)°. The dichloromethane solvent molecule is disordered over four sets of sites with occupancies of 0.3:0.3:0.2:0.2. |
| format | Text |
| id | pubmed-3051605 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2011 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-30516052011-04-26 (μ-Benzoato-κ(2) O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ(2) N:N′]dimolybdenum(II) dichloromethane monosolvate Han, L.-J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mo(2)(C(15)H(15)N(2)O(2))(3)(C(7)H(5)O(2))]·CH(2)Cl(2), has a quadruply bonded Mo(2) (4+) unit equatorially coordinated by three N,N′-bis(4-μ-methoxyphenyl)formamidinate (DAniF) ligands and one benzoate anion. The Mo—Mo bond length of 2.0881 (8) Å is typical for quadruply bonded species. The phenyl ring and the connected dimetal chelating ring (Mo(2)O(2)C) are nearly co-planar, making a dihedral angle of 3.24 (13)°. The dichloromethane solvent molecule is disordered over four sets of sites with occupancies of 0.3:0.3:0.2:0.2. International Union of Crystallography 2011-01-26 /pmc/articles/PMC3051605/ /pubmed/21522909 http://dx.doi.org/10.1107/S1600536811002558 Text en © L.-J. Han 2011 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Han, L.-J. (μ-Benzoato-κ(2) O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ(2) N:N′]dimolybdenum(II) dichloromethane monosolvate |
| title | (μ-Benzoato-κ(2)
O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ(2)
N:N′]dimolybdenum(II) dichloromethane monosolvate |
| title_full | (μ-Benzoato-κ(2)
O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ(2)
N:N′]dimolybdenum(II) dichloromethane monosolvate |
| title_fullStr | (μ-Benzoato-κ(2)
O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ(2)
N:N′]dimolybdenum(II) dichloromethane monosolvate |
| title_full_unstemmed | (μ-Benzoato-κ(2)
O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ(2)
N:N′]dimolybdenum(II) dichloromethane monosolvate |
| title_short | (μ-Benzoato-κ(2)
O:O′)tris[μ-N,N′-bis(4-methoxyphenyl)formamidinato-κ(2)
N:N′]dimolybdenum(II) dichloromethane monosolvate |
| title_sort | (μ-benzoato-κ(2)
o:o′)tris[μ-n,n′-bis(4-methoxyphenyl)formamidinato-κ(2)
n:n′]dimolybdenum(ii) dichloromethane monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3051605/ https://www.ncbi.nlm.nih.gov/pubmed/21522909 http://dx.doi.org/10.1107/S1600536811002558 |
| work_keys_str_mv | AT hanlj mbenzoatok2ootrismnnbis4methoxyphenylformamidinatok2nndimolybdenumiidichloromethanemonosolvate |